Organic electroluminescent materials and devices

ABSTRACT

A compound having the formula Ir(L A ) n (L B ) 3-n , having the structure 
     
       
         
         
             
             
         
       
     
     of Formula I is provided. In the structure of Formula I, each of A 1  through A 8  is independently carbon or nitrogen; at least one of A 1  through A 8  is nitrogen; ring B is bonded to ring A through a C—C bond; the iridium is bonded to ring A through an Ir—C bond; X is O, S, or Se; each of R 1  through R 5  are independently selected from a variety of substituents, whichmay be linked for form a ring; n is an integer from 1 to 3; and at least one R 2  adjacent to ring C is not hydrogen. Formulations and devices, such as OLEDs, that include the first compound are also provided.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. Ser. No. 15/449,307, filed Mar. 3, 2017, which claims priority to U.S. Provisional Patent Application Ser. No. 62/405,406, filed Oct. 7, 2016, the entire contents of which is incorporated herein by reference.

FIELD

The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.

More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.

SUMMARY

According to one embodiment, a compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n), having the structure

of Formula I is provided. In the structure of Formula I:

each of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is independently carbon or nitrogen;

at least one of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is nitrogen;

ring B is bonded to ring A through a C—C bond;

the iridium is bonded to ring A through an Ir—C bond;

X is O, S, or Se;

R¹, R², R³, R⁴, and R⁵ independently represent from mono-substituted to the maximum possibly substitutions, or no substitution;

any adjacent substitutions in R², R³, and R⁵ are optionally linked together to form a ring;

R¹, R², R³, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;

n is an integer from 1 to 3; and

at least one R² adjacent to ring C is not hydrogen.

According to another embodiment, an organic light emitting diode/device (OLED) is also provided. The OLED can include an anode, a cathode, and an organic layer, disposed between the anode and the cathode. The organic layer can include a compound of Formula Ir(L_(A))_(n)(L_(B))_(3-n). According to yet another embodiment, the organic light emitting device is incorporated into one or more device selected from a consumer product, an electronic component module, and/or a lighting panel.

According to yet another embodiment, a formulation containing a compound of Formula Ir(L_(A))_(n)(L_(B))_(3-n) is provided.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranchcd, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

The term “halo,” “halogen,” or “halide” as used herein includes fluorine, chlorine, bromine, and iodine.

The term “alkyl” as used herein contemplates both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.

The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 10 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.

The term “alkenyl” as used herein contemplates both straight and branched chain alkene radicals. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.

The term “alkynyl” as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.

The term “heterocyclic group” as used herein contemplates aromatic and non-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also means heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperdino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.

The term “aryl” or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.

The term “heteroaryl” as used herein contemplates single-ring hetero-aromatic groups that may include from one to five heteroatoms. The term heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophcnodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.

The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be unsubstituted or may be substituted with one or more substituents selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant position, such as carbon. Thus, for example, where R′ is mono-substituted, then one R′ must be other than H. Similarly, where R′ is di-substituted, then two of R′ must be other than H. Similarly, where R′ is unsubstituted, R′ is hydrogen for all available positions.

The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.

According to one embodiment, a compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n), having the structure

of Formula I is described. In the structure of Formula I:

each of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is independently carbon or nitrogen;

at least one of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is nitrogen;

ring B is bonded to ring A through a C—C bond;

the iridium is bonded to ring A through an Ir—C bond;

X is O, S, or Se;

R¹, R², R³, R⁴, and R⁵ independently represent from mono-substituted to the maximum possibly substitutions, or no substitution;

any adjacent substitutions in R¹, R², le, R⁴, and R⁵ are optionally linked together to form a ring;

R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfanyl, sulfonyl, phosphino, and combinations thereof;

n is an integer from 1 to 3; and

at least one R² adjacent to ring C is not hydrogen.

In some embodiments, n is 1.

In some embodiments, the compound is selected from the group consisting of:

In some embodiments, only one of A¹ to A⁸ is nitrogen. In some embodiments, A¹ to A⁴ are carbon, and exactly one of A⁵ to A⁸ is nitrogen.

In some embodiments, X is O.

In some embodiments, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, partial fluorinated alkyl, partial fluorinated cycloalkyl, and combinations thereof. In some embodiments, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, and cyclohexyl.

In some embodiments, the compound is selected from the group consisting of

In some such embodiments, the R¹ next to N is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variants thereof, partially fluorinated variants thereof, and combinations thereof. In some such embodiments, the R′ next to N is selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, and partially or fully deuterated variations thereof.

In some embodiments, L_(A) is selected from the group consisting of L_(Ap,1) to L_(Ap,634) and L_(Am,1) to L_(Am,634), where L_(Ap,i) and L_(Am,i) have structures

where i is an integer from 1 to 634. In such embodiments, L_(Ap,1) to L_(Ap,634) and L_(Am,1) to L_(Am,634), the substituents R^(A1), R^(A2), R^(A2), and R^(A4) are defined as follows:

i R^(A1) R^(A2) R^(A3) R^(A4) 1. CH₃ H H H 2. CH₃ CH₃ H CH₃ 3. CH₃ H CH₃ H 4. CH₃ H H CH₃ 5. CH₃ CH₃ CH₃ H 6. CH₃ CH₃ H CH₃ 7. CH₃ H CH₃ CH₃ 8. CH₃ CH₃ CH₃ CH₃ 9. CH₂CH₃ H H H 10. CH₂CH₃ CH₃ H CH₃ 11. CH₂CH₃ H CH₃ H 12. CH₂CH₃ H H CH₃ 13. CH₂CH₃ CH₃ CH₃ H 14. CH₂CH₃ CH₃ H CH₃ 15. CH₂CH₃ H CH₃ CH₃ 16. CH₂CH₃ CH₃ CH₃ CH₃ 17. CH₃ CH₂CH₃ H CH₃ 18. CH₃ CH₂CH₃ CH₃ H 19. CH₃ CH₂CH₃ H CH₃ 20. CH₃ CH₂CH₃ CH₃ CH₃ 21. CH₃ H CH₂CH₃ H 22. CH₃ CH₃ CH₂CH₃ H 23. CH₃ H CH₂CH₃ CH₃ 24. CH₃ CH₃ CH₂CH₃ CH₃ 25. CH(CH₃)₂ H H H 26. CH(CH₃)₂ CH₃ H CH₃ 27. CH(CH₃)₂ H CH₃ H 28. CH(CH₃)₂ H H CH₃ 29. CH(CH₃)₂ CH₃ CH₃ H 30. CH(CH₃)₂ CH₃ H CH₃ 31. CH(CH₃)₂ H CH₃ CH₃ 32. CH(CH₃)₂ CH₃ CH₃ CH₃ 33. CH₃ CH(CH₃)₂ H CH₃ 34. CH₃ CH(CH₃)₂ CH₃ H 35. CH₃ CH(CH₃)₂ H CH₃ 36. CH₃ CH(CH₃)₂ CH₃ CH₃ 37. CH₃ H CH(CH₃)₂ H 38. CH₃ CH₃ CH(CH₃)₂ H 39. CH₃ H CH(CH₃)₂ CH₃ 40. CH₃ CH₃ CH(CH₃)₂ CH₃ 41. CH₂CH(CH₃)₂ H H H 42. CH₂CH(CH₃)₂ CH₃ H CH₃ 43. CH₂CH(CH₃)₂ H CH₃ H 44. CH₂CH(CH₃)₂ H H CH₃ 45. CH₂CH(CH₃)₂ CH₃ CH₃ H 46. CH₂CH(CH₃)₂ CH₃ H CH₃ 47. CH₂CH(CH₃)₂ H CH₃ CH₃ 48. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃ 49. CH₃ CH₂CH(CH₃)₂ H CH₃ 50. CH₃ CH₂CH(CH₃)₂ CH₃ H 51. CH₃ CH₂CH(CH₃)₂ H CH₃ 52. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃ 53. CH₃ H CH₂CH(CH₃)₂ H 54. CH₃ CH₃ CH₂CH(CH₃)₂ H 55. CH₃ H CH₂CH(CH₃)₂ CH₃ 56. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃ 57. C(CH₃)₃ H H H 58. C(CH₃)₃ CH₃ H CH₃ 59. C(CH₃)₃ H CH₃ H 60. C(CH₃)₃ H H CH₃ 61. C(CH₃)₃ CH₃ CH₃ H 62. C(CH₃)₃ CH₃ H CH₃ 63. C(CH₃)₃ H CH₃ CH₃ 64. C(CH₃)₃ CH₃ CH₃ CH₃ 65. CH₃ C(CH₃)₃ H CH₃ 66. CH₃ C(CH₃)₃ CH₃ H 67. CH₃ C(CH₃)₃ H CH₃ 68. CH₃ C(CH₃)₃ CH₃ CH₃ 69. CH₃ H C(CH₃)₃ H 70. CH₃ CH₃ C(CH₃)₃ H 71. CH₃ H C(CH₃)₃ CH₃ 72. CH₃ CH₃ C(CH₃)₃ CH₃ 73. CH₂C(CH₃)₃ H H H 74. CH₂C(CH₃)₃ CH₃ H CH₃ 75. CH₂C(CH₃)₃ H CH₃ H 76. CH₂C(CH₃)₃ H H CH₃ 77. CH₂C(CH₃)₃ CH₃ CH₃ H 78. CH₂C(CH₃)₃ CH₃ H CH₃ 79. CH₂C(CH₃)₃ H CH₃ CH₃ 80. CH₂C(CH₃)₃ CH₃ CH₃ CH₃ 81. CH₃ CH₂C(CH₃)₃ H CH₃ 82. CH₃ CH₂C(CH₃)₃ CH₃ H 83. CH₃ CH₂C(CH₃)₃ H CH₃ 84. CH₃ CH₂C(CH₃)₃ CH₃ CH₃ 85. CH₃ H CH₂C(CH₃)₃ H 86. CH₃ CH₃ CH₂C(CH₃)₃ H 87. CH₃ H CH₂C(CH₃)₃ CH₃ 88. CH₃ CH₃ CH₂C(CH₃)₃ CH₃ 89. CH₂C(CH₃)₂CF₃ H H H 90. CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 91. CH₂C(CH₃)₂CF₃ H CH₃ H 92. CH₂C(CH₃)₂CF₃ H H CH₃ 93. CH₂C(CH₃)₂CF₃ CH₃ CH₃ H 94. CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 95. CH₂C(CH₃)₂CF₃ H CH₃ CH₃ 96. CH₂C(CH₃)₂CF₃ CH₃ CH₃ CH₃ 97. CH₃ CH₂C(CH₃)₂CF₃ H CH₃ 98. CH₃ CH₂C(CH₃)₂CF₃ CH₃ H 99. CH₃ CH₂C(CH₃)₂CF₃ H CH₃ 100. CH₃ CH₂C(CH₃)₂CF₃ CH₃ CH₃ 101. CH₃ H CH₂C(CH₃)₂CF₃ H 102. CH₃ CH₃ CH₂C(CH₃)₂CF₃ H 103. CH₃ H CH₂C(CH₃)₂CF₃ CH₃ 104. CH₃ CH₃ CH₂C(CH₃)₂CF₃ CH₃ 105. CH₂CH₂CF₃ H H H 106. CH₂CH₂CF₃ CH₃ H CH₃ 107. CH₂CH₂CF₃ H CH₃ H 108. CH₂CH₂CF₃ H H CH₃ 109. CH₂CH₂CF₃ CH₃ CH₃ H 110. CH₂CH₂CF₃ CH₃ H CH₃ 111. CH₂CH₂CF₃ H CH₃ CH₃ 112. CH₂CH₂CF₃ CH₃ CH₃ CH₃ 113. CH₃ CH₂CH₂CF₃ H CH₃ 114. CH₃ CH₂CH₂CF₃ CH₃ H 115. CH₃ CH₂CH₂CF₃ H CH₃ 116. CH₃ CH₂CH₂CF₃ CH₃ CH₃ 117. CH₃ H CH₂CH₂CF₃ H 118. CH₃ CH₃ CH₂CH₂CF₃ H 119. CH₃ H CH₂CH₂CF₃ CH₃ 120. CH₃ CH₃ CH₂CH₂CF₃ CH₃ 121.

H H H 122.

CH₃ H CH₃ 123.

H CH₃ H 124.

H H CH₃ 125.

CH₃ CH₃ H 126.

CH₃ H CH₃ 127.

H CH₃ CH₃ 128.

CH₃ CH₃ CH₃ 129. CH₃

H CH₃ 130. CH₃

CH₃ H 131. CH₃

H CH₃ 132. CH₃

CH₃ CH₃ 133. CH₃ H

H 134. CH₃ CH₃

H 135. CH₃ H

CH₃ 136. CH₃ CH₃

CH₃ 137.

H H H 138.

CH₃ H CH₃ 139.

H CH₃ H 140.

H H CH₃ 141.

CH₃ CH₃ H 142.

CH₃ H CH₃ 143.

H CH₃ CH₃ 144.

CH₃ CH₃ CH₃ 145. CH₃

H CH₃ 146. CH₃

CH₃ H 147. CH₃

H CH₃ 148. CH₃

CH₃ CH₃ 149. CH₃ H

H 150. CH₃ CH₃

H 151. CH₃ H

CH₃ 152. CH₃ CH₃

CH₃ 153.

H H H 154.

CH₃ H CH₃ 155.

H CH₃ H 156.

H H CH₃ 157.

CH₃ CH₃ H 158.

CH₃ H CH₃ 159.

H CH₃ CH₃ 160.

CH₃ CH₃ CH₃ 161. CH₃

H CH₃ 162. CH₃

CH₃ H 163. CH₃

H CH₃ 164. CH₃

CH₃ CH₃ 165. CH₃ H

H 166. CH₃ CH₃

H 167. CH₃ H

CH₃ 168. CH₃ CH₃

CH₃ 169.

H H H 170.

CH₃ H CH₃ 171.

H CH₃ H 172.

H H CH₃ 173.

CH₃ CH₃ H 174.

CH₃ H CH₃ 175.

H CH₃ CH₃ 176.

CH₃ CH₃ CH₃ 177. CH₃

H CH₃ 178. CH₃

CH₃ H 179. CH₃

H CH₃ 180. CH₃

CH₃ CH₃ 181. CH₃ H

H 182. CH₃ CH₃

H 183. CH₃ H

CH₃ 184. CH₃ CH₃

CH₃ 185.

H H H 186.

CH₃ H CH₃ 187.

H CH₃ H 188.

H H CH₃ 189.

CH₃ CH₃ H 190.

CH₃ H CH₃ 191.

H CH₃ CH₃ 192.

CH₃ CH₃ CH₃ 193. CH₃

H CH₃ 194. CH₃

CH₃ H 195. CH₃

H CH₃ 196. CH₃

CH₃ CH₃ 197. CH₃ H

H 198. CH₃ CH₃

H 199. CH₃ H

CH₃ 200. CH₃ CH₃

CH₃ 201.

H H H 202.

CH₃ H CH₃ 203.

H CH₃ H 204.

H H CH₃ 205.

CH₃ CH₃ H 206.

CH₃ H CH₃ 207.

H CH₃ CH₃ 208.

CH₃ CH₃ CH₃ 209. CH₃

H CH₃ 210. CH₃

CH₃ H 211. CH₃

H CH₃ 212. CH₃

CH₃ CH₃ 213. CH₃ H

H 214. CH₃ CH₃

H 215. CH₃ H

CH₃ 216. CH₃ CH₃

CH₃ 217. CH(CH₃)₂ H CH₂CH₃ H 218. CH(CH₃)₂ H CH(CH₃)₂ H 219. CH(CH₃)₂ H CH₂CH(CH₃)₂ H 220. CH(CH₃)₂ H C(CH₃)₃ H 221. CH(CH₃)₂ H CH₂C(CH₃)₃ H 222. CH(CH₃)₂ H CH₂CH₂CF₃ H 223. CH(CH₃)₂ H CH₂C(CH₃)₂CF H 224. CH(CH₃)₂ H

H 225. CH(CH₃)₂ H

H 226. CH(CH₃)₂ H

H 227. CH(CH₃)₂ H

H 228. CH(CH₃)₂ H

H 229. CH(CH₃)₂ H

H 230. C(CH₃)₃ H CH₂CH₃ H 231. C(CH₃)₃ H CH(CH₃)₂ H 232. C(CH₃)₃ H CH₂CH(CH₃)₂ H 233. C(CH₃)₃ H C(CH₃)₃ H 234. C(CH₃)₃ H CH₂C(CH₃)₃ H 235. C(CH₃)₃ H CH₂CH₂CF₃ H 236. C(CH₃)₃ H CH₂C(CH₃)₂CF₃ 237. C(CH₃)₃ H

H 238. C(CH₃)₃ H

H 239. C(CH₃)₃ H

H 240. C(CH₃)₃ H

H 241. C(CH₃)₃ H

H 242. C(CH₃)₃ H

H 243. CH₂C(CH₃)₃ H CH₂CH₃ H 244. CH₂C(CH₃)₃ H CH(CH₃)₂ H 245. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H 246. CH₂C(CH₃)₃ H C(CH₃)₃ H 247. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H 248. CH₂C(CH₃)₃ H CH₂CH₂CF₃ 249. CH₂C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H 250. CH₂C(CH₃)₃ H

H 251. CH₂C(CH₃)₃ H

H 252. CH₂C(CH₃)₃ H

H 253. CH₂C(CH₃)₃ H

H 254. CH₂C(CH₃)₃ H

H 255. CH₂C(CH₃)₃ H

H 256.

H CH₂CH₃ H 257.

H CH(CH₃)₂ H 258.

H CH₂CH(CH₃)₂ H 259.

H C(CH₃)₃ H 260.

H CH₂C(CH₃)₃ H 261.

H CH₂CH₂CF₃ H 262.

H CH₂C(CH₃)₂CF₃ H 263.

H

H 264.

H

H 265.

H

H 266.

H

H 267.

H

H 268.

H

H 269.

H CH₂CH₃ H 270.

H CH(CH₃)₂ H 271.

H CH₂CH(CH₃)₂ H 272.

H C(CH₃)₃ H 273.

H CH₂C(CH₃)₃ H 274.

H CH₂CH₂CF₃ H 275.

H CH₂C(CH₃)₂CF₃ H 276.

H

H 277.

H

H 278.

H

H 279.

H

H 280.

H

H 281.

H

H 282.

H CH₂CH(CH₃)₂ H 283.

H C(CH₃)₃ H 284.

H CH₂C(CH₃)₃ H 285.

H CH₂CH₂CF₃ H 286.

H CH₂C(CH₃)₂CF₃ H 287.

H

H 288.

H

H 289.

H

H 290.

H

H 291.

H

H 292.

H

H 293.

H CH₂CH(CH₃)₂ H 294.

H C(CH₃)₃ 295.

H CH₂C(CH₃)₃ H 296.

H CH₂CH₂CF₃ H 297.

H CH₂C(CH₃)₂CF₃ H 298.

H

H 299.

H

H 300.

H

H 301.

H

H 302.

H

H 303.

H

H 304.

H CH₂CH(CH₃)₂ H 305.

H C(CH₃)₃ H 306.

H CH₂C(CH₃)₃ H 307.

H CH₂CH₂CF₃ H 308.

H CH₂C(CH₃)₂CF₃ H 309.

H

H 310.

H

H 311.

H

H 312.

H

H 313.

H

H 314.

H

H 315. CD₃ H H H 316. CD₃ CD₃ H CD₃ 317. CD₃ H CD₃ H 318. CD₃ H H CD₃ 319. CD₃ CD₃ CD₃ H 320. CD₃ CD₃ H CD₃ 321. CD₃ H CD₃ CD₃ 322. CD₃ CD₃ CD₃ CD₃ 323. CD₂CH₃ H H H 324. CD₂CH₃ CD₃ H CD₃ 325. CD₂CH₃ H CD₃ H 326. CD₂CH₃ H H CD₃ 327. CD₂CH₃ CD₃ CD₃ H 328. CD₂CH₃ CD₃ H CD₃ 329. CD₂CH₃ H CD₃ CD₃ 330. CD₂CH₃ CD₃ CD₃ CD₃ 331. CH₃ CD₂CH₃ H CD₃ 332. CD₃ CD₂CH₃ CD₃ H 333. CD₃ CD₂CH₃ H CD₃ 334. CD₃ CD₂CH₃ CD₃ CD₃ 335. CD₃ H CD₂CH₃ H 336. CD₃ CD₃ CD₂CH₃ H 337. CD₃ H CD₂CH₃ CD₃ 338. CD₃ CD₃ CD₂CH₃ CD₃ 339. CD(CH₃)₂ H H H 340. CD(CH₃)₂ CD₃ H CD₃ 341. CD(CH₃)₂ H CD₃ H 342. CD(CH₃)₂ H H CD₃ 343. CD(CH₃)₂ CD₃ CD₃ H 344. CD(CH₃)₂ CD₃ H CD₃ 345. CD(CH₃)₂ H CD₃ CD₃ 346. CD(CH₃)₂ CD₃ CD₃ CD₃ 347. CD₃ CD(CH₃)₂ H CD₃ 348. CD₃ CD(CH₃)₂ CD₃ H 349. CD₃ CD(CH₃)₂ H CD₃ 350. CD₃ CD(CH₃)₂ CD₃ CD₃ 351. CD₃ H CD(CH₃)₂ H 352. CD₃ CD₃ CD(CH₃)₂ H 353. CD₃ H CD(CH₃)₂ CD₃ 354. CD₃ CD₃ CD(CH₃)₂ CD₃ 355. CD(CD₃)₂ H H H 356. CD(CD₃)₂ CD₃ H CD₃ 357. CD(CD₃)₂ H CD₃ H 358. CD(CD₃)₂ H H CD₃ 359. CD(CD₃)₂ CD₃ CD₃ H 360. CD(CD₃)₂ CD₃ H CD₃ 361. CD(CD₃)₂ H CD₃ CD₃ 362. CD(CD₃)₂ CD₃ CD₃ CD₃ 363. CH₃ CD(CD₃)₂ H CD₃ 364. CD₃ CD(CD₃)₂ CD₃ H 365. CD₃ CD(CD₃)₂ H CD₃ 366. CD₃ CD(CD₃)₂ CD₃ CD₃ 367 CD₃ H CD(CD₃)₂ H 368. CD₃ CD₃ CD(CD₃)₂ H 369. CD₃ H CD(CD₃)₂ CD₃ 370. CD₃ CD₃ CD(CD₃)₂ CD₃ 371. CD₂CH(CH₃)₂ H H H 372. CD₂CH(CH₃)₂ CD₃ H CD₃ 373. CD₂CH(CH₃)₂ H CD₃ H 374. CD₂CH(CH₃)₂ H H CD₃ 375. CD₂CH(CH₃)₂ CD₃ CD₃ H 376. CD₂CH(CH₃)₂ CD₃ H CD₃ 377. CD₂CH(CH₃)₂ H CD₃ CD₃ 378. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃ 379. CD₃ CD₂CH(CH₃)₂ H CD₃ 380. CD₃ CD₂CH(CH₃)₂ CD₃ H 381. CD₃ CD₂CH(CH₃)₂ H CD₃ 382. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃ 383. CD₃ H CD₂CH(CH₃)₂ H 384. CD₃ CD₃ CD₂CH(CH₃)₂ H 385. CD₃ H CD₂CH(CH₃)₂ CD₃ 386. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃ 387. CD₂C(CH₃)₃ H H H 388. CD₂C(CH₃)₃ CD₃ H CD₃ 389. CD₂C(CH₃)₃ H CD₃ H 390. CD₂C(CH₃)₃ H H CD₃ 391. CD₂C(CH₃)₃ CD₃ CD₃ H 392. CD₂C(CH₃)₃ CD₃ H CD₃ 393. CD₂C(CH₃)₃ H CD₃ CD₃ 394. CD₂C(CH₃)₃ CH₃ CD₃ CD₃ 395. CD₃ CD₂C(CH₃)₃ H CD₃ 396. CD₃ CD₂C(CH₃)₃ CD₃ H 397. CD₃ CD₂C(CH₃)₃ H CD₃ 398. CD₃ CD₂C(CH₃)₃ CD₃ CD₃ 399. CD₃ H CD₂C(CH₃)₃ H 400. CD₃ CD₃ CD₂C(CH₃)₃ H 401. CD₃ H CD₂C(CH₃)₃ CD₃ 402. CD₃ CD₃ CD₂C(CH₃)₃ CD₃ 403. CD₂C(CH₃)₂CF₃ H H H 404. CD₂C(CH₃)₂CF₃ CD₃ H CD₃ 405. CD₂C(CH₃)₂CF₃ H CD₃ H 406. CD₂C(CH₃)₂CF₃ H H CD₃ 407. CD₂C(CH₃)₂CF₃ CD₃ CD₃ H 408. CD₂C(CH₃)₂CF₃ CD₃ H CD₃ 409. CD₂C(CH₃)₂CF₃ H CD₃ CD₃ 410. CD₂C(CH₃)₂CF₃ CD₃ CD₃ CD₃ 411. CD₃ CD₂C(CH₃)₂CF₃ H CD₃ 412. CD₃ CD₂C(CH₃)₂CF₃ CD₃ H 413. CD₃ CD₂C(CH₃)₂CF₃ H CD₃ 414. CD₃ CD₂C(CH₃)₂CF₃ CD₃ CD₃ 415. CD₃ H CD₂C(CH₃)₂CF₃ H 416. CD₃ CD₃ CD₂C(CH₃)₂CF₃ H 417. CD₃ H CD₂C(CH₃)₂CF₃ CD₃ 418. CD₃ CD₃ CD₂C(CH₃)₂CF₃ CD₃ 419. CD₂CH₂CF₃ H H H 420. CD₂CH₂CF₃ CD₃ H CD₃ 421. CD₂CH₂CF₃ H CD₃ H 422. CD₂CH₂CF₃ H H CD₃ 423. CD₂CH₂CF₃ CD₃ CD₃ H 424. CD₂CH₂CF₃ CD₃ H CD₃ 425. CD₂CH₂CF₃ H CD₃ CD₃ 426. CD₂CH₂CF₃ CD₃ CD₃ CD₃ 427. CD₃ CD₂CH₂CF₃ H CD₃ 428. CD₃ CD₂CH₂CF₃ CD₃ H 429. CD₃ CD₂CH₂CF₃ H CD₃ 430. CD₃ CD₂CH₂CF₃ CD₃ CD₃ 431. CD₃ H CD₂CH₂CF₃ H 432. CD₃ CD₃ CD₂CH₂CF₃ H 433. CD₃ H CD₂CH₂CF₃ CD₃ 434. CD₃ CD₃ CD₂CH₂CF₃ CD₃ 435.

H H H 436.

CD₃ H CD₃ 437.

H CD₃ H 438.

H H CD₃ 439.

CD₃ CD₃ H 440.

CD₃ H CD₃ 441.

H CD₃ CD₃ 442.

CD₃ CD₃ CD₃ 443. CD₃

H CD₃ 444. CD₃

CD₃ H 445. CD₃

H CD₃ 446. CD₃

CD₃ CD₃ 447. CD₃ H

H 448. CD₃ CD₃

H 449. CD₃ H

CD₃ 450. CD₃ CD₃

CD₃ 451.

H H H 452.

CD₃ H CD₃ 453.

H CD₃ H 454.

H H CD₃ 455.

CD₃ CD₃ H 456.

CD₃ H CD₃ 457.

H CD₃ CD₃ 458.

CD₃ CD₃ CD₃ 459. CH₃

H CD₃ 460. CD₃

CD₃ H 461. CD₃

H CD₃ 462. CH₃

CD₃ CD₃ 463. CD₃ H

H 464. CD₃ CD₃

H 465. CD₃ H

CD₃ 466. CD₃ CD₃

CD₃ 467.

H H H 468.

CD₃ H CD₃ 469.

H CD₃ H 470.

H H CD₃ 471.

CD₃ CD₃ H 472.

CD₃ H CD₃ 473.

H CD₃ CD₃ 474.

CD₃ CD₃ CD₃ 475. CD₃

H CD₃ 476. CD₃

CD₃ H 477. CD₃

H CD₃ 478. CD₃

CD₃ CD₃ 479. CD₃ H

H 480. CD₃ CD₃

H 481. CD₃ H

CD₃ 482. CD₃ CD₃

CD₃ 483.

H H H 484.

CD₃ H CD₃ 485.

H CD₃ H 486.

H H CD₃ 487.

CD CD₃ H 488.

CD₃ H CD₃ 489.

H CD₃ CD₃ 490.

CD₃ CD₃ CD₃ 491. CD₃

H CD₃ 492. CD₃

CD₃ H 493. CD₃

H CD₃ 494. CD₃

CD₃ CD₃ 495. CD₃ H

H 496. CD₃ CD₃

H 497. CD₃ H

CD₃ 498. CD₃ CD₃

CD₃ 499.

H H H 500.

CD₃ H CD₃ 501.

H CD₃ H 502.

H H CD₃ 503.

CD₃ CD₃ H 504.

CD₃ H CD₃ 505.

H CD₃ CD₃ 506.

CD₃ CD₃ CD₃ 507. CD₃

H CD₃ 508. CD₃

CD₃ H 509. CD₃

H CD₃ 510. CD₃

CD₃ CD₃ 511. CD₃ H

H 512. CD₃ CD₃

H 513. CD₃ H

CD₃ 514. CD₃ CD₃

CD₃ 515.

H H H 516.

CD₃ H CD₃ 517.

H CD₃ H 518.

H H CD₃ 519.

CH₃ CH₃ H 520.

CD₃ H CD₃ 521.

H CD₃ CD₃ 522.

CD₃ CD₃ CD₃ 523. CD₃

H CD₃ 524. CD₃

CD₃ H 525. CD₃

H CD₃ 526. CD₃

CD₃ CD₃ 527. CD₃ H

H 528. CD₃ CD₃

H 529. CD₃ H

CD₃ 530. CD₃ CD₃

CD₃ 531. CD(CH₃)₂ H CD₂CH₃ H 532. CD(CH₃)₂ H CD(CH₃)₂ H 533. CD(CH₃)₂ H CD₂CH(CH₃)₂ H 534. CD(CH₃)₂ H C(CH₃)₃ H 535. CD(CH₃)₂ H CD₂C(CH₃)₃ H 536. CD(CH₃)₂ H CD₂CH₂CF₃ H 537. CD(CH₃)₂ H CD₂C(CH₃)₂CF₃ H 538. CD(CH₃)₂ H

H 539. CD(CH₃)₂ H

H 540. CD(CH₃)₂ H

H 541. CD(CH₃)₂ H

H 542. CD(CH₃)₂ H

H 543. CD(CH₃)₂ H

H 544. C(CH₃)₃ H CD₂CH₃ H 545. C(CH₃)₃ H CD(CH₃)₂ H 546. C(CH₃)₃ H CD₂CH(CH₃)₂ H 547. C(CH₃)₃ H C(CH₃)₃ H 548. C(CH₃)₃ H CD₂C(CH₃)₃ H 549. C(CH₃)₃ H CD₂CH₂CF₃ H 550. C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H 551. C(CH₃)₃ H

H 552. C(CH₃)₃ H

H 553. C(CH₃)₃ H

H 554. C(CH₃) H

H 555. C(CH₃)₃ H

H 556. C(CH₃)₃ H

H 557. CD₂C(CH₃)₃ H CD₂CH₃ H 558. CD₂C(CH₃)₃ H CD(CH₃)₂ H 559. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H 560. CD₂C(CH₃)₃ H C(CH₃)₃ H 561. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H 562. CD₂C(CH₃)₃ H CD₂CH₂CF₃ H 563. CD₂C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H 564. CD₂C(CH₃)₃ H

H 565. CD₂C(CH₃)₃ H

H 566. CD₂C(CH₃)₃ H

H 567. CD₂C(CH₃)₃ H

H 568. CD₂C(CH₃)₃ H

H 569. CD₂C(CH₃)₃ H

H 570.

H CD₂CH₃ H 571.

H CD(CH₃)₂ H 572.

H CD₂CH(CH₃)₂ H 573.

H C(CH₃)₃ H 574.

H CD₂C(CH₃)₃ H 575.

H CD₂CH₂CF₃ H 576.

H CD₂C(CH₃)₂CF₃ H 577.

H

H 578.

H

H 579.

H

H 580.

H

H 581.

H

H 582.

H

H 583.

H CD₂CH₃ H 584.

H CD(CH₃)₂ H 585.

H CD₂CH(CH₃)₂ H 586.

H C(CH₃)₃ H 587.

H CD₂C(CH₃)₃ H 588.

H CD₂CH₂CF₃ H 589.

H CD₂C(CH₃)₂CF₃ H 590.

H

H 591.

H

H 592.

H

H 593.

H

H 594.

H

H 595.

H

H 596.

H CD₂CH₃ H 597.

H CD(CH₃)₂ H 598.

H CD₂CH(CH₃)₂ H 599.

H C(CH₃)₃ H 600.

H CD₂C(CH₃)₃ H 601.

H CD₂CH₂CF₃ H 602.

H CD₂C(CH₃)₂CF₃ H 603.

H

H 604.

H

H 605.

H

H 606.

H

H 607.

H

H 608.

H

H 609.

H CD₂CH₃ H 610.

H CD(CH₃)₂ H 611.

H CD₂CH(CH₃)₂ H 612.

H C(CH₃)₃ H 613.

H CD₂C(CH₃)₃ H 614.

H CD₂CH₂CF₃ H 615.

H CD₂C(CH₃)₂CF₃ H 616.

H

H 617.

H

H 618.

H

H 619.

H

H 620.

H

H 621.

H

H 622.

H CD₂CH₃ H 623.

H CD(CH₃)₂ H 624.

H CD₂CH(CH₃)₂ H 625.

H C(CH₃)₃ H 626.

H CD₂C(CH₃)₃ H 627.

H CD₂CH₂CF₃ H 628.

H CD₂C(CH₃)₂CF₃ H 629.

H

H 630.

H

H 631.

H

H 632.

H

H 633.

H

H 634.

H

H

In some embodiments, L_(B) is selected from the group consisting of L_(B1) to L_(B856), where L_(B,b) has the structure:

wherein b is an integer from 1 to 856, and the substituents R^(B1), R^(B2), R^(B3) and R^(B4) are defined as follows:

b R^(B1) R^(B2) R^(B3) R^(B4) 1. H H H H 2. CH₃ H H H 3. H CH₃ H H 4. H H CH₃ H 5. CH₃ CH₃ H CH₃ 6. CH₃ H CH₃ H 7. CH₃ H H CH₃ 8. H CH₃ CH₃ H 9. H CH₃ H CH₃ 10. H H CH₃ CH₃ 11. CH₃ CH₃ CH₃ H 12. CH₃ CH₃ H CH₃ 13. CH₃ H CH₃ CH₃ 14. H CH₃ CH₃ CH₃ 15. CH₃ CH₃ CH₃ CH₃ 16. CH₂CH₃ H H H 17. CH₂CH₃ CH₃ H CH₃ 18. CH₂CH₃ H CH₃ H 19. CH₂CH₃ H H CH₃ 20. CH₂CH₃ CH₃ CH₃ H 21. CH₂CH₃ CH₃ H CH₃ 22. CH₂CH₃ H CH₃ CH₃ 23. CH₂CH₃ CH₃ CH₃ CH₃ 24. H CH₂CH₃ H H 25. CH₃ CH₂CH₃ H CH₃ 26. H CH₂CH₃ CH₃ H 27. H CH₂CH₃ H CH₃ 28. CH₃ CH₂CH₃ CH₃ H 29. CH₃ CH₂CH₃ H CH₃ 30. H CH₂CH₃ CH₃ CH₃ 31. CH₃ CH₂CH₃ CH₃ CH₃ 32. H H CH₂CH₃ H 33. CH₃ H CH₂CH₃ H 34. H CH₃ CH₂CH₃ H 35. H H CH₂CH₃ CH₃ 36. CH₃ CH₃ CH₂CH₃ H 37. CH₃ H CH₂CH₃ CH₃ 38. H CH₃ CH₂CH₃ CH₃ 39. CH₃ CH₃ CH₂CH₃ CH₃ 40. CH(CH₃)₂ H H H 41. CH(CH₃)₂ CH₃ H CH₃ 42. CH(CH₃)₂ H CH₃ H 43. CH(CH₃)₂ H H CH₃ 44. CH(CH₃)₂ CH₃ CH₃ H 45. CH(CH₃)₂ CH₃ H CH₃ 46. CH(CH₃)₂ H CH₃ CH₃ 47. CH(CH₃)₂ CH₃ CH₃ CH₃ 48. H CH(CH₃)₂ H H 49. CH₃ CH(CH₃)₂ H CH₃ 50. H CH(CH₃)₂ CH₃ H 51. H CH(CH₃)₂ H CH₃ 52. CH₃ CH(CH₃)₂ CH₃ H 53. CH₃ CH(CH₃)₂ H CH₃ 54. H CH(CH₃)₂ CH₃ CH₃ 55. CH₃ CH(CH₃)₂ CH₃ CH₃ 56. H H CH(CH₃)₂ H 57. CH₃ H CH(CH₃)₂ H 58. H CH₃ CH(CH₃)₂ H 59. H H CH(CH₃)₂ CH₃ 60. CH₃ CH₃ CH(CH₃)₂ H 61. CH₃ H CH(CH₃)₂ CH₃ 62. H CH₃ CH(CH₃)₂ CH₃ 63. CH₃ CH₃ CH(CH₃)₂ CH₃ 64. CH₂CH(CH₃)₂ H H H 65. CH₂CH(CH₃)₂ CH₃ H CH₃ 66. CH₂CH(CH₃)₂ H CH₃ H 67. CH₂CH(CH₃)₂ H H CH₃ 68. CH₂CH(CH₃)₂ CH₃ CH₃ H 69. CH₂CH(CH₃)₂ CH₃ H CH₃ 70. CH₂CH(CH₃)₂ H CH₃ CH₃ 71. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃ 72. H CH₂CH(CH₃)₂ H H 73. CH₃ CH₂CH(CH₃)₂ H CH₃ 74. H CH₂CH(CH₃)₂ CH₃ H 75. H CH₂CH(CH₃)₂ H CH₃ 76. CH₃ CH₂CH(CH₃)₂ CH₃ H 77. CH₃ CH₂CH(CH₃)₂ H CH₃ 78. H CH₂CH(CH₃)₂ CH₃ CH₃ 79. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃ 80. H H CH₂CH(CH₃)₂ H 81. CH₃ H CH₂CH(CH₃)₂ H 82. H CH₃ CH₂CH(CH₃)₂ H 83. H H CH₂CH(CH₃)₂ CH₃ 84. CH₃ CH₃ CH₂CH(CH₃)₂ H 85. CH₃ H CH₂CH(CH₃)₂ CH₃ 86. H CH₃ CH₂CH(CH₃)₂ CH₃ 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃ 88. C(CH₃)₃ H H H 89. C(CH₃)₃ CH₃ H CH₃ 90. C(CH₃)₃ H CH₃ H 91. C(CH₃)₃ H H CH₃ 92. C(CH₃)₃ CH₃ CH₃ H 93. C(CH₃)₃ CH₃ H CH₃ 94. C(CH₃)₃ H CH₃ CH₃ 95. C(CH₃)₃ CH₃ CH₃ CH₃ 96. H C(CH₃)₃ H H 97. CH₃ C(CH₃)₃ H CH₃ 98. H C(CH₃)₃ CH₃ H 99. H C(CH₃)₃ H CH₃ 100. CH₃ C(CH₃)₃ CH₃ H 101. CH₃ C(CH₃)₃ H CH₃ 102. H C(CH₃)₃ CH₃ CH₃ 103. CH₃ C(CH₃)₃ CH₃ CH₃ 104. H H C(CH₃)₃ H 105. CH₃ H C(CH₃)₃ H 106. H CH₃ C(CH₃)₃ H 107. H H C(CH₃)₃ CH₃ 108. CH₃ CH₃ C(CH₃)₃ H 109. CH₃ H C(CH₃)₃ CH₃ 110. H CH₃ C(CH₃)₃ CH₃ 111. CH₃ CH₃ C(CH₃)₃ CH₃ 112. CH₂C(CH₃)₃ H H H 113. CH₂C(CH₃)₃ CH₃ H CH₃ 114. CH₂C(CH₃)₃ H CH₃ H 115. CH₂C(CH₃)₃ H H CH₃ 116. CH₂C(CH₃)₃ CH₃ CH₃ H 117. CH₂C(CH₃)₃ CH₃ H CH₃ 118. CH₂C(CH₃)₃ H CH₃ CH₃ 119. CH₂C(CH₃)₃ CH₃ CH₃ CH₃ 120. H CH₂C(CH₃)₃ H H 121. CH₃ CH₂C(CH₃)₃ H CH₃ 122. H CH₂C(CH₃)₃ CH₃ H 123. H CH₂C(CH₃)₃ H CH₃ 124. CH₃ CH₂C(CH₃)₃ CH₃ H 125. CH₃ CH₂C(CH₃)₃ H CH₃ 126. H CH₂C(CH₃)₃ CH₃ CH₃ 127. CH₃ CH₂C(CH₃)₃ CH₃ CH₃ 128. H H CH₂C(CH₃)₃ H 129. CH₃ H CH₂C(CH₃)₃ H 130. H CH₃ CH₂C(CH₃)₃ H 131. H H CH₂C(CH₃)₃ CH₃ 132. CH₃ CH₃ CH₂C(CH₃)₃ H 133. CH₃ H CH₂C(CH₃)₃ CH₃ 134. H CH₃ CH₂C(CH₃)₃ CH₃ 135. CH₃ CH₃ CH₂C(CH₃)₃ CH₃ 136. CH₂C(CH₃)₂CF₃ H H H 137. CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 138. CH₂C(CH₃)₂CF₃ H CH₃ H 139. CH₂C(CH₃)₂CF₃ H H CH₃ 140. CH₂C(CH₃)₂CF₃ CH₃ CH₃ H 141. CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 142. CH₂C(CH₃)₂CF₃ H CH₃ CH₃ 143. CH₂C(CH₃)₂CF₃ CH₃ CH₃ CH₃ 144. H CH₂C(CH₃)₂CF₃ H H 145. CH₃ CH₂C(CH₃)₂CF₃ H CH₃ 146. H CH₂C(CH₃)₂CF₃ CH₃ H 147. H CH₂C(CH₃)₂CF₃ H CH₃ 148. CH₃ CH₂C(CH₃)₂CF₃ CH₃ H 149. CH₃ CH₂C(CH₃)₂CF₃ H CH₃ 150. H CH₂C(CH₃)₂CF₃ CH₃ CH₃ 151. CH₃ CH₂C(CH₃)₂CF₃ CH₃ CH₃ 152. H H CH₂C(CH₃)₂CF₃ H 153. CH₃ H CH₂C(CH₃)₂CF₃ H 154. H CH₃ CH₂C(CH₃)₂CF₃ H 155. H H CH₂C(CH₃)₂CF₃ CH₃ 156. CH₃ CH₃ CH₂C(CH₃)₂CF₃ H 157. CH₃ H CH₂C(CH₃)₂CF₃ CH₃ 158. H CH₃ CH₂C(CH₃)₂CF₃ CH₃ 159. CH₃ CH₃ CH₂C(CH₃)₂CF₃ CH₃ 160. CH₂CH₂CF₃ H H H 161. CH₂CH₂CF₃ CH₃ H CH₃ 162. CH₂CH₂CF₃ H CH₃ H 163. CH₂CH₂CF₃ H H CH₃ 164. CH₂CH₂CF₃ CH₃ CH₃ H 165. CH₂CH₂CF₃ CH₃ H CH₃ 166. CH₂CH₂CF₃ H CH₃ CH₃ 167. CH₂CH₂CF₃ CH₃ CH₃ CH₃ 168. H CH₂CH₂CF₃ H H 169. CH₃ CH₂CH₂CF₃ H CH₃ 170. H CH₂CH₂CF₃ CH₃ H 171. H CH₂CH₂CF₃ H CH₃ 172. CH₃ CH₂CH₂CF₃ CH₃ H 173. CH₃ CH₂CH₂CF₃ H CH₃ 174. H CH₂CH₂CF₃ CH₃ CH₃ 175. CH₃ CH₂CH₂CF₃ CH₃ CH₃ 176. H H CH₂CH₂CF₃ H 177. CH₃ H CH₂CH₂CF₃ H 178. H CH₃ CH₂CH₂CF₃ H 179. H H CH₂CH₂CF₃ CH₃ 180. CH₃ CH₃ CH₂CH₂CF₃ H 181. CH₃ H CH₂CH₂CF₃ CH₃ 182. H CH₃ CH₂CH₂CF₃ CH₃ 183. CH₃ CH₃ CH₂CH₂CF₃ CH₃ 184.

H H H 185.

CH₃ H CH₃ 186.

H CH₃ H 187.

H H CH₃ 188.

CH₃ CH₃ H 189.

CH₃ H CH₃ 190.

H CH₃ CH₃ 191.

CH₃ CH₃ CH₃ 192. H

H H 193. CH₃

H CH₃ 194. H

CH₃ H 195. H

H CH₃ 196. CH₃

CH₃ H 197. CH₃

H CH₃ 198. H

CH₃ CH₃ 199. CH₃

CH₃ CH₃ 200. H H

H 201. CH₃ H

H 202. H CH₃

H 203. H H

CH₃ 204. CH₃ CH₃

H 205. CH₃ H

CH₃ 206. H CH₃

CH₃ 207. CH₃ CH₃

CH₃ 208.

H H H 209.

CH₃ H CH₃ 210.

H CH₃ H 211.

H H CH₃ 212.

CH₃ CH₃ H 213.

CH₃ H CH₃ 214.

H CH₃ CH₃ 215.

CH₃ CH₃ CH₃ 216. H

H H 217. CH₃

H CH₃ 218. H

CH₃ H 219. H

H CH₃ 220. CH₃

CH₃ H 221. CH₃

H CH₃ 222. H

CH₃ CH₃ 223. CH₃

CH₃ CH₃ 224. H H

H 225. CH₃ H

H 226. H CH₃

H 227. H H

CH₃ 228. CH₃ CH₃

H 229. CH₃ H

CH₃ 230. H CH₃

CH₃ 231. CH₃ CH₃

CH₃ 232.

H H H 233.

CH₃ H CH₃ 234.

H CH₃ H 235.

H H CH₃ 236.

CH₃ CH₃ H 237.

CH₃ H CH₃ 238.

H CH₃ CH₃ 239.

CH₃ CH₃ CH₃ 240. H

H H 241. CH₃

H CH₃ 242. H

CH₃ H 243. H

H CH₃ 244. CH₃

CH₃ H 245. CH₃

H CH₃ 246. H

CH₃ CH₃ 247. CH₃

CH₃ CH₃ 248. H H

H 249. CH₃ H

H 250. H CH₃

H 251. H H

CH₃ 252. CH₃ CH₃

H 253. CH₃ H

CH₃ 254. H CH₃

CH₃ 255. CH₃ CH₃

CH₃ 256.

H H H 257.

CH₃ H CH₃ 258.

H CH₃ H 259.

H H CH₃ 260.

CH₃ CH₃ H 261.

CH₃ H CH₃ 262.

H CH₃ CH₃ 263.

CH₃ CH₃ CH₃ 264. H

H H 265. CH₃

H CH₃ 266. H

CH₃ H 267. H

H CH₃ 268. CH₃

CH₃ H 269. CH₃

H CH₃ 270. H

CH₃ CH₃ 271. CH₃

CH₃ CH₃ 272. H H

H 273. CH₃ H

H 274. H CH₃

H 275. H H

CH₃ 276. CH₃ CH₃

H 277. CH₃ H

CH₃ 278. H CH₃

CH₃ 279. CH₃ CH₃

CH₃ 280.

H H H 281.

CH₃ H CH₃ 282.

H CH₃ H 283.

H H CH₃ 284.

CH₃ CH₃ H 285.

CH₃ H CH₃ 286.

H CH₃ CH₃ 287.

CH₃ CH₃ CH) 288. H

H H 289. CH₃

H CH₃ 290. H

CH₃ H 291. H

H CH₃ 292. CH₃

CH₃ H 293. CH₃

H CH₃ 294. H

CH₃ CH₃ 295. CH₃

CH₃ CH₃ 296. H H

H 297. CH₃ H

H 298. H CH₃

H 299. H H

CH₃ 300. CH₃ CH₃

H 301. CH₃ H

CH₃ 302. H CH₃

CH₃ 303. CH₃ CH₃

CH₃ 304.

H H H 305.

CH₃ H CH₃ 306.

H CH₃ H 307.

H H CH₃ 308.

CH₃ CH₃ H 309.

CH₃ H CH₃ 310.

H CH₃ CH₃ 311.

CH₃ CH₃ CH₃ 312. H

H H 313. CH₃

H CH₃ 314. H

CH₃ H 315. H

H CH₃ 316. CH₃

CH₃ H 317. CH₃

H CH₃ 318. H

CH₃ CH₃ 319. CH₃

CH₃ CH₃ 320. H H

H 321. CH₃ H

H 322. H CH₃

H 323. H H

CH₃ 324. CH₃ CH₃

H 325. CH₃ H

CH₃ 326. H CH₃

CH₃ 327. CH₃ CH₃

CH₃ 328. CH(CH₃)₂ H CH₂CH₃ H 329. CH(CH₃)₂ H CH(CH₃)₂ H 330. CH(CH₃)₂ H CH₂CH(CH₃)₂ H 331. CH(CH₃)₂ H C(CH₃)₃ H 332. CH(CH₃)₂ H CH₂C(CH₃)₃ H 333. CH(CH₃)₂ H CH₂CH₂CF₃ H 334. CH(CH₃)₂ H CH₂C(CH₃)CF₃ H 335. CH(CH₃)₂ H

H 336. CH(CH₃)₂ H

H 337. CH(CH₃)₂ H

H 338. CH(CH₃)₂ H

H 339. CH(CH₃)₂ H

H 340. CH(CH₃)₂ H

H 341. C(CH₃)₃ H CH₂CH₃ H 342. C(CH₃)₃ H CH(CH₃)₂ H 343. C(CH₃)₃ H CH₂CH(CH₃)₂ H 344. C(CH₃)₃ H C(CH₃)₃ H 345. C(CH₃)₃ H CH₂C(CH₃)₃ H 346. C(CH₃)₃ H CH₂CH₂CF₃ H 347. C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H 348. C(CH₃)₃ H

H 349. C(CH₃)₃ H

H 350. C(CH₃)₃ H

H 351. C(CH₃)₃ H

H 352. C(CH₃)₃ H

H 353. C(CH₃)₃ H

H 354. CH₂C(CH₃)₃ H CH₂CH₃ H 355. CH₂C(CH₃)₃ H CH(CH₃)₂ H 356. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H 357. CH₂C(CH₃)₃ H C(CH₃)₃ H 358. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H 359. CH₂C(CH₃)₃ H CH₂CH₂CF₃ H 360. CH₂C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H 361. CH₂C(CH₃)₃ H

H 362. CH₂C(CH₃)₃ H

H 363. CH₂C(CH₃)₃ H

H 364. CH₂C(CH₃)₃ H

H 365. CH₂C(CH₃)₃ H

H 366. CH₂C(CH₃)₃ H

H 367.

H CH₂CH₃ H 368.

H CH(CH₃)₂ H 369.

H CH₂CH(CH₃)₂ H 370.

H C(CH₃)₃ H 371.

H CH₂C(CH₃)₃ H 372.

H CH₂CH₂CF₃ H 373.

H CH₂C(CH₃)₂CF₃ H 374.

H

H 375.

H

H 376.

H

H 377.

H

H 378.

H

H 379.

H

H 380.

H CH₂CH₃ H 381.

H CH(CH₃)₂ H 382.

H CH₂CH(CH₃)₂ H 383.

H C(CH₃)₃ H 384.

H CH₂C(CH₃)₃ H 385.

H CH₂CH₂CF₃ H 386.

H CH₂C(CH₃)₂CF₃ H 387.

H

H 388.

H

H 389.

H

H 390.

H

H 391.

H

H 392.

H

H 393.

H CH₂CH(CH₃)₂ H 394.

H C(CH₃)₃ H 395.

H CH₂C(CH₃)₃ H 396.

H CH₂CH₂CF₃ H 397.

H CH₂C(CH₃)₂CF₃ H 398.

H

H 399.

H

H 400.

H

H 401.

H

H 402.

H

H 403.

H

H 404.

H CH₂CH(CH₃)₂ H 405.

H C(CH₃)₃ H 406.

H CH₂C(CH₃)₃ H 407.

H CH₂CH₂CF₃ H 408.

H CH₂C(CH₃)₂CF₃ H 409.

H

H 410.

H

H 411.

H

H 412.

H

H 413.

H

H 414.

H

H 415.

H CH₂CH(CH₃)₂ H 416.

H C(CH₃)₃ H 417.

H CH₂C(CH₃)₃ H 418.

H CH₂CH₂CF₃ H 419.

H CH₂C(CH₃)₂CF₃ H 420.

H

H 421.

H

H 422.

H

H 423.

H

H 424.

H

H 425.

H

H 426. H H H H 427. CD₃ H H H 428. H CD₃ H H 429. H H CD₃ H 430. CD₃ CD₃ H CD₃ 431. CD₃ H CD₃ H 432. CD₃ H H CD₃ 433. H CD₃ CH₃ H 434. H CD₃ H CD₃ 435. H H CD₃ CD₃ 436. CD₃ CD₃ CD₃ H 437. CD₃ CD₃ H CD₃ 438. CD₃ H CD₃ CD₃ 439. H CD₃ CD₃ CD₃ 440. CD₃ CD₃ CD₃ CD₃ 441. CD₂CH₃ H H H 442. CD₂CH₃ CD₃ H CD₃ 443. CD₂CH₃ H CD₃ H 444. CD₂CH₃ H H CD₃ 445. CD₂CH₃ CD₃ CD₃ H 446. CD₂CH₃ CD₃ H CD₃ 447. CD₂CH₃ H CD₃ CD₃ 448. CD₂CH₃ CD₃ CD₃ CD₃ 449. H CD₂CH₃ H H 450. CH₃ CD₂CH₃ H CD₃ 451. H CD₂CH₃ CD₃ H 452. H CD₂CH₃ H CD₃ 453. CD₃ CD₂CH₃ CD₃ H 454. CD₃ CD₂CH₃ H CD₃ 455. H CD₂CH₃ CD₃ CD₃ 456. CD₃ CD₂CH₃ CD₃ CD₃ 457. H H CD₂CH₃ H 458. CD₃ H CD₂CH₃ H 459. H CD₃ CD₂CH₃ H 460. H H CD₂CH₃ CD₃ 461. CD₃ CD₃ CD₂CH₃ H 462. CD₃ H CD₂CH₃ CD₃ 463. H CD₃ CD₂CH₃ CD₃ 464. CD₃ CD₃ CD₂CH₃ CD₃ 465. CD(CH₃)₂ H H H 466. CD(CH₃)₂ CD₃ H CD₃ 467. CD(CH₃)₂ H CD₃ H 468. CD(CH₃)₂ H H CD₃ 469. CD(CH₃)₂ CD₃ CD₃ H 470. CD(CH₃)₂ CD₃ H CD₃ 471. CD(CH₃)₂ H CD₃ CD₃ 472. CD(CH₃)₂ CD₃ CD₃ CD₃ 473. H CD(CH₃)₂ H H 474. CD₃ CD(CH₃)₂ H CD₃ 475. H CD(CH₃)₂ CD₃ H 476. H CD(CH₃)₂ H CD₃ 477. CD₃ CD(CH₃)₂ CD₃ H 478. CD₃ CD(CH₃)₂ H CD₃ 479. H CD(CH₃)₂ CD₃ CD₃ 480. CD₃ CD(CH₃)₂ CD₃ CD₃ 481. H H CD(CH₃)₂ H 482. CD₃ H CD(CH₃)₂ H 483. H CD₃ CD(CH₃)₂ H 484. H H CD(CH₃)₂ CD₃ 485. CD₃ CD₃ CD(CH₃)₂ H 486. CD₃ H CD(CH₃)₂ CD₃ 487. H CD₃ CD(CH₃)₂ CD₃ 488. CD₃ CD₃ CD(CH₃)₂ CD₃ 489. CD(CD₃)₂ H H H 490. CD(CD₃)₂ CD₃ H CD₃ 491. CD(CD₃)₂ H CD₃ H 492. CD(CD₃)₂ H H CD₃ 493. CD(CD₃)₂ CD₃ CD₃ H 494. CD(CD₃)₂ CD₃ H CD₃ 495. CD(CD₃)₂ H CD₃ CD₃ 496. CD(CD₃)₂ CD₃ CD₃ CD₃ 497. H CD(CD₃)₂ H H 498. CH₃ CD(CD₃)₂ H CD₃ 499. H CD(CD₃)₂ CD₃ H 500. H CD(CD₃)₂ H CD₃ 501. CD₃ CD(CD₃)₂ CD₃ H 502. CD₃ CD(CD₃)₂ H CD₃ 503. H CD(CD₃)₂ CD₃ CD₃ 504. CD₃ CD(CD₃)₂ CD₃ CD₃ 505. H H CD(CD₃)₂ H 506. CD₃ H CD(CD₃)₂ H 507. H CD₃ CD(CD₃)₂ H 508. H H CD(CD₃)₂ CD₃ 509. CD₃ CD₃ CD(CD₃)₂ H 510. CD₃ H CD(CD₃)₂ CD₃ 511. H CD₃ CD(CD₃)₂ CD₃ 512. CD₃ CD₃ CD(CD₃)₂ CD₃ 513. CD₂CH(CH₃)₂ H H H 514. CD₂CH(CH₃)₂ CD₃ H CD₃ 515. CD₂CH(CH₃)₂ H CD₃ H 516. CD₂CH(CH₃)₂ H H CD₃ 517. CD₂CH(CH₃)₂ CD₃ CD₃ H 518. CD₂CH(CH₃)₂ CD₃ H CD₃ 519. CD₂CH(CH₃)₂ H CD₃ CD₃ 520. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃ 521. H CD₂CH(CH₃)₂ H H 522. CD₃ CD₂CH(CH₃)₂ H CD₃ 523. H CD₂CH(CH₃)₂ CD₃ H 524. H CD₂CH(CH₃)₂ H CD₃ 525. CD₃ CD₂CH(CH₃)₂ CD₃ H 526. CD₃ CD₂CH(CH₃)₂ H CD₃ 527. H CD₂CH(CH₃)₂ CD₃ CD₃ 528. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃ 529. H H CD₂CH(CH₃)₂ H 530. CD₃ H CD₂CH(CH₃)₂ H 531. H CD₃ CD₂CH(CH₃)₂ H 532. H H CD₂CH(CH₃)₂ CD₃ 533. CD₃ CD₃ CD₂CH(CH₃)₂ H 534. CD₃ H CD₂CH(CH₃)₂ CD₃ 535. H CD₃ CD₂CH(CH₃)₂ CD₃ 536. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃ 537. CD₂C(CH₃)₃ H H H 538. CD₂C(CH₃)₃ CD₃ H CD₃ 539. CD₂C(CH₃)₃ H CD₃ H 540. CD₂C(CH₃)₃ H H CD₃ 541. CD₂C(CH₃)₃ CD₃ CD₃ H 542. CD₂C(CH₃)₃ CD₃ H CD₃ 543. CD₂C(CH₃)₃ H CD₃ CD₃ 544. CD₂C(CH₃)₃ CH₃ CD₃ CD₃ 545. H CD₂C(CH₃)₃ H H 546. CD₃ CD₂C(CH₃)₃ H CD₃ 547. H CD₂C(CH₃)₃ CD₃ H 548. H CD₂C(CH₃)₃ H CD₃ 549. CD₃ CD₂C(CH₃)₃ CD₃ H 550. CD₃ CD₂C(CH₃)₃ H CD₃ 551. H CD₂C(CH₃)₃ CD₃ CD₃ 552. CD₃ CD₂C(CH₃)₃ CD₃ CD₃ 553. H H CD₂C(CH₃)₃ H 554. CD₃ H CD₂C(CH₃)₃ H 555. H CD₃ CD₂C(CH₃)₃ H 556. H H CD₂C(CH₃)₃ CD₃ 557. CD₃ CD₃ CD₂C(CH₃)₃ H 558. CD₃ H CD₂C(CH₃)₃ CD₃ 559. H CD₃ CD₂C(CH₃)₃ CD₃ 560. CD₃ CD₃ CD₂C(CH₃)₃ CD₃ 561. CD₂C(CH₃)₂CF₃ H H H 562. CD₂C(CH₃)₂CF₃ CD₃ H CD₃ 563. CD₂C(CH₃)₂CF₃ H CD₃ H 564. CD₂C(CH₃)₂CF₃ H H CD₃ 565. CD₂C(CH₃)₂CF₃ CD₃ CD₃ H 566. CD₂C(CH₃)₂CF₃ CD₃ H CD₃ 567. CD₂C(CH₃)₂CF₃ H CD₃ CD₃ 568. CD₂C(CH₃)₂CF₃ CD₃ CD₃ CD₃ 569. H CD₂C(CH₃)₂CF₃ H H 570. CD₃ CD₂C(CH₃)₂CF₃ H CD₃ 571. H CD₂C(CH₃)₂CF₃ CD₃ H 572. H CD₂C(CH₃)₂CF₃ H CD₃ 573. CD₃ CD₂C(CH₃)₂CF₃ CD₃ H 574. CD₃ CD₂C(CH₃)₂CF₃ H CD₃ 575. H CD₂C(CH₃)₂CF₃ CD₃ CD₃ 576. CD₃ CD₂C(CH₃)₂CF₃ CD₃ CD₃ 577. H H CD₂C(CH₃)₂CF₃ H 578. CD₃ H CD₂C(CH₃)₂CF₃ H 579. H CD₃ CD₂C(CH₃)₂CF₃ H 580. H H CD₂C(CH₃)₂CF₃ CD₃ 581. CD₃ CD₃ CD₂C(CH₃)₂CF₃ H 582. CD₃ H CD₂C(CH₃)₂CF₃ CD₃ 583. H CD₃ CD₂C(CH₃)₂CF₃ CD₃ 584. CD₃ CD₃ CD₂C(CH₃)₂CF₃ CD₃ 585. CD₂CH₂CF₃ H H H 586. CD₂CH₂CF₃ CD₃ H CD₃ 587. CD₂CH₂CF₃ H CD₃ H 588. CD₂CH₂CF₃ H H CD₃ 589. CD₂CH₂CF₃ CD₃ CD₃ H 590. CD₂CH₂CF₃ CD₃ H CD₃ 591. CD₂CH₂CF₃ H CD₃ CD₃ 592. CD₂CH₂CF₃ CD₃ CD₃ CD₃ 593. H CD₂CH₂CF₃ H H 594. CD₃ CD₂CH₂CF₃ H CD₃ 595. H CD₂CH₂CF₃ CD₃ H 596. H CD₂CH₂CF₃ H CD₃ 597. CD₃ CD₂CH₂CF₃ CD₃ H 598. CD₃ CD₂CH₂CF₃ H CD₃ 599. H CD₂CH₂CF₃ CD₃ CD₃ 600. CD₃ CD₂CH₂CF₃ CD₃ CD₃ 601. H H CD₂CH₂CF₃ H 602. CD₃ H CD₂CH₂CF₃ H 603. H CD₃ CD₂CH₂CF₃ H 604. H H CD₂CH₂CF₃ CD₃ 605. CD₃ CD₃ CD₂CH₂CF₃ H 606. CD₃ H CD₂CH₂CF₃ CD₃ 607. H CD₃ CD₂CH₂CF₃ CD₃ 608. CD₃ CD₃ CD₂CH₂CF₃ CD₃ 609.

H H H 610.

CD₃ H CD₃ 611.

H CD₃ H 612.

H H CD₃ 613.

CD₃ CD₃ H 614.

CD₃ H CD₃ 615.

H CD₃ CD₃ 616.

CD₃ CD₃ CD₃ 617. H

H H 618. CD₃

H CD₃ 619. H

CD₃ H 620. H

H CD₃ 621. CD₃

CD₃ H 622. CD₃

H CD₃ 623. H

CD₃ CD₃ 624. CD₃

CD₃ CD₃ 625. H H

H 626. CD₃ H

H 627. H CD₃

H 628. H H

CD₃ 629. CD₃ CD₃

H 630. CD₃ H

CD₃ 631. H CD₃

CD₃ 632. CD₃ CD₃

CD₃ 633.

H H H 634.

CD₃ H CD₃ 635.

H CD₃ H 636.

H H CD₃ 637.

CD₃ CD₃ H 638.

CD₃ H CD₃ 639.

H CD₃ CD₃ 640.

CD₃ CD₃ CD₃ 641. H

H H 642. CH₃

H CD₃ 643. H

CD₃ H 644. H

H CD₃ 645. CD₃

CD₃ H 646. CD₃

H CD₃ 647. H

CD₃ CD₃ 648. CH₃

CD₃ CD₃ 649. H H

H 650. CD₃ H

H 651. H CD₃

H 652. H H

CD₃ 653. CD₃ CD₃

H 654. CD₃ H

CD₃ 655. H CD₃

CD₃ 656. CD₃ CD₃

CD₃ 657.

H H H 658.

CD₃ H CD₃ 659.

H CD₃ H 660.

H H CD₃ 661.

CD₃ CD₃ H 662.

CD₃ H CD₃ 663.

H CD₃ CD₃ 664.

CD₃ CD₃ CD₃ 665. H

H H 666. CD₃

H CD₃ 667. H

CD₃ H 668. H

H CD₃ 669. CD₃

CD₃ H 670. CD₃

H CD₃ 671. H

CD₃ CD₃ 672. CD₃

CD₃ CD₃ 673. H H

H 674. CD₃ H

H 675. H CD₃

H 676. H H

CD₃ 677. CD₃ CD₃

H 678. CD₃ H

CD₃ 679. H CD₃

CD₃ 680. CD₃ CD₃

CD₃ 681.

H H H 682.

CD₃ H CD₃ 683.

H CD₃ H 684.

H H CD₃ 685.

CD₃ CD₃ H 686.

CD₃ H CD₃ 687.

H CD₃ CD₃ 688.

CD₃ CD₃ CD₃ 689. H

H H 690. CD₃

H CD₃ 691. H

CD₃ H 692. H

H CD₃ 693. CD₃

CD₃ H 694. CD₃

H CD₃ 695. H

CD₃ CD₃ 696. CD₃

CD₃ CD₃ 697. H H

H 698. CD₃ H

H 699. H CD₃

H 700. H H

CD₃ 701. CD₃ CD₃

H 702. CD₃ H

CD₃ 703. H CD₃

CD₃ 704. CD₃ CD₃

CD₃ 705.

H H H 706.

CD₃ H CD₃ 707.

H CD₃ H 708.

H H CD₃ 709.

CD₃ CD₃ H 710.

CD₃ H CD₃ 711.

H CD₃ CD₃ 712.

CD₃ CD₃ CD₃ 713. H

H H 714. CD₃

H CD₃ 715. H

CD₃ H 716. H

H CD₃ 717. CD₃

CD₃ H 718. CD₃

H CD₃ 719. H

CD₃ CD₃ 720. CD₃

CD₃ CD₃ 721. H H

H 722. CD₃ H

H 723. H CD₃

H 724. H H

CD₃ 725. CD₃ CD₃

H 726. CD₃ H

CD₃ 727. H CD₃

CD₃ 728. CD₃ CD₃

CD₃ 729.

H H H 730.

CD₃ H CD₃ 731.

H CD₃ H 732.

H H CD₃ 733.

CH₃ CH₃ H 734.

CD₃ H CD₃ 735.

H CD₃ CD₃ 736.

CD₃ CD₃ CD₃ 737. H

H H 738. CD₃

H CD₃ 739. H

CD₃ H 740. H

H CD₃ 741. CD₃

CD₃ H 742. CD₃

H CD₃ 743. H

CD₃ CD₃ 744. CD₃

CD₃ CD₃ 745. H H

H 746. CD₃ H

H 747. H CD₃

H 748. H H

CH₃ 749. CD₃ CD₃

H 750. CD₃ H

CD₃ 751. H CD₃

CD₃ 752. CD₃ CD₃

CD₃ 753. CD(CH₃)₂ H CD₂CH₃ H 754. CD(CH₃)₂ H CD(CH₃)₂ H 755. CD(CH₃)₂ H CD₂CH(CH₃)₂ H 756. CD(CH₃)₂ H C(CH₃)₃ H 757. CD(CH₃)₂ H CD₂C(CH₃)₃ H 758. CD(CH₃)₂ H CD₂CH₂CF₃ H 759. CD(CH₃)₂ H CD₂C(CH₃)₂CF₃ H 760. CD(CH₃)₂ H

H 761. CD(CH₃)₂ H

H 762. CD(CH₃)₂ H

H 763. CD(CH₃)₂ H

H 764. CD(CH₃)₂ H

H 765. CD(CH₃)₂ H

H 766. C(CH₃)₃ H CD₂CH₃ H 767. C(CH₃)₃ H CD(CH₃)₂ H 768. C(CH₃)₃ H CD₂CH(CH₃)₂ H 769. C(CH₃)₃ H C(CH₃)₃ H 770. C(CH₃)₃ H CD₂C(CH₃)₃ H 771. C(CH₃)₃ H CD₂CH₂CF₃ H 772. C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H 773. C(CH₃)₃ H

H 774. C(CH₃)₃ H

H 775. C(CH₃)₃ H

H 776. C(CH₃)₃ H

H 777. C(CH₃)₃ H

H 778. C(CH₃)₃ H

H 779. CD₂C(CH₃)₃ H CD₂CH₃ H 780. CD₂C(CH₃)₃ H CD(CH₃)₂ H 781. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H 782. CD₂C(CH₃)₃ H C(CH₃)₃ H 783. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H 784. CD₂C(CH₃)₃ H CD₂CH₂CF₃ H 785. CD₂C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H 786. CD₂C(CH₃)₃ H

H 787. CD₂C(CH₃)₃ H

H 788. CD₂C(CH₃)₃ H

H 789. CD₂C(CH₃)₃ H

H 790. CD₂C(CH₃)₃ H

H 791. CD₂C(CH₃)₃ H

H 792.

H CD₂CH₃ H 793.

H CD(CH₃)₂ H 794.

H CD₂CH(CH₃)₂ H 795.

H C(CH₃)₃ H 796.

H CD₂C(CH₃)₃ H 797.

H CD₂CH₂CF₃ H 798.

H CD₂C(CH₃)₂CF₃ H 799.

H

H 800.

H

H 801.

H

H 802.

H

H 803.

H

H 804.

H

H 805.

H CD₂CH₃ H 806.

H CD(CH₃)₂ H 807.

H CD₂CH(CH₃)₂ H 808.

H C(CH₃)₃ H 809.

H CD₂C(CH₃)₃ H 810.

H CD₂CH₂CF₃ H 811.

H CD₂C(CH₃)₂CF₃ H 812.

H

H 813.

H

H 814.

H

H 815.

H

H 816.

H

H 817.

H

H 818.

H CD₂CH₃ H 819.

H CD(CH₃)₂ H 820.

H CD₂CH(CH₃)₂ H 821.

H C(CH₃)₃ H 822.

H CD₂C(CH₃)₃ H 823.

H CD₂CH₂CF₃ H 824.

H CD₂C(CH₃)₂CF₃ H 825.

H

H 826.

H

H 827.

H

H 828.

H

H 829.

H

H 830.

H

H 831.

H CD₂CH₃ H 832.

H CD(CH₃)₂ H 833.

H CD₂CH(CH₃)₂ H 834.

H C(CH₃)₃ H 835.

H CD₂C(CH₃)₃ H 836.

H CD₂CH₂CF₃ H 837.

H CD₂C(CH₃)₂CF₃ H 838.

H

H 839.

H

H 840.

H

H 841.

H

H 842.

H

H 843.

H

H 844.

H CD₂CH₃ H 845.

H CD(CH₃)₂ H 846.

H CD₂CH(CH₃)₂ H 847.

H C(CH₃)₃ H 848.

H CD₂C(CH₃)₃ H 849.

H CD₂CH₂CF₃ H 850.

H CD₂C(CH₃)₂CF₃ H 851.

H

H 852.

H

H 853.

H

H 854.

H

H 855.

H

H 856.

H

H

In some embodiments, the compound is selected from the group consisting of Compound 1 through Compound 1,085,408, where:

-   -   (1) for Compound 1 through Compound 542,704, Compound x has the         formula Ir(L_(Ap,i))(L_(Bj))₂; where x=856i+j−856; i is an         integer from 1 to 634, and j is an integer from 1 to 856, and     -   (II) for Compound 542,705 through Compound 1,085,408, Compound x         has the formula Ir(L_(Am,i))(L_(Bj))₂; where x=856i+j+541,848; i         is an integer from 1 to 634, and j is an integer from 1 to 856;

In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

In another embodiments, an organic light emitting device (OLED) that includes an anode; a cathode; and an organic layer, disposed between the anode and the cathode is described. The organic layer can include a compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n) and its variants as described herein.

The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1), C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has no substitution. In the preceding substituents n can range from 1 to 10; and Ar₁ and Ar₂ can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:

and combinations thereof. Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation that comprises a compound according to Formula Ir(L_(A))_(n)(L_(B))_(3-n) is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.

Combination with Other Materials

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 and US2012146012.

HIL/HTL:

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/FSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO_(x); a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the group consisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH) or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40; (Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independently selected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In another aspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

EBL:

An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.

Host:

The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have the following general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴ are independently selected from C, N, O, P, and S; L¹⁰¹ is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

Examples of other organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the following groups in the molecule:

wherein each of R¹⁰¹ to R¹⁰⁷ is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfonyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20; k′″ is an integer from 0 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N. Z¹⁰¹ and Z¹⁰² is selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.

HBL: A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than one or more of the hosts closest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ is an integer from 1 to 3.

ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar¹ to Ar³ has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L′° ‘ is another ligand; k’ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.

EXPERIMENTAL Synthesis of Compound 275205

Step 1:

4-lodo-1,2-dimethylbenzene (12.9 g, 55.6 mmol) was charged into the reaction flask with dimethyl sulfoxide-d6 (D6-DMSO)(60 ml, 857 mmol) followed by sodium tert-butoxide (1.8 g, 18.75 mmol). This mixture was degassed with nitrogen then was stirred at 65° C. for 18 hours. The reaction was cooled down and quenched with 75 mL of D₂O. This mixture was stirred at room temperature (˜22° C.) for 45 minutes. The mixture was then diluted with 200 mL of water and was extracted with 3×70 mL of dichloromethane (DCM). These extracts were dried over magnesium sulfate, filtered and concentrated under vacuum. The crude residue was subjected to column chromatography on silica gel eluted with DCM/heptanes 95/5 (v/v). Pure fractions were combined and concentrated under vacuum yielding 4-iodo-1,2-bis(methyl-d3)benzene (12.1 g, 50.8 mmol, 91% yield).

Step 2

4-iodo-1,2-bis(methyl-d3)benzene (16.9 g, 71.0 mmol), 4,4,4′,4′,5,5,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborolane) (19.83 g, 78 mmol), and 1,1′-bis(diphenylphosphino)ferrocene-palladium(II) dichloride (2.030 g, 2.484 mmol) were charged into the reaction flask with 200 mL of dioxane, followed by the addition of potassium acetate (14.61 g, 149 mmol). This mixture was degassed with nitrogen then heated to reflux for 18 hours. The reaction mixture was cooled down to room temperature (˜22° C.), then dioxane was removed under vacuum. The crude material was diluted with 300 mL of water and extracted with 3×70 mL of DCM. These extracts were dried over magnesium sulfate, filtered and concentrated under vacuum. The crude residue was subjected to column chromatography on silica gel elated with DCM/heptanes 40/60 to 70/30 (v/v) gradient mixture, yielding 2-(3,4-bis(methyl-d3)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (11.5 g, 48.3 mmol, 68.0% yield) as a dark oil.

Step 3

8-(4-chloro-5-methylpyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (6.2 g, 20.08 mmol), 2-(3,4-bis(methyl-d3)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (8.37 g, 35.1 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (SPhos) (1.6 g, 3.90 mmol), and tris(dibenzylideneacetone)palladium(0) (Pd₂(dba)₃) (0.643 g, 0.703 mmol) were charged into the reaction flask with 350 mL of 1,2-dimethoxyethane (DME). Potassium phosphate tribasic monohydrate (23.09 g, 100 mmol) was dissolved in 50 mL of water then charged into the reaction flask. This mixture was degassed and heated to reflux for 18 hours. The reaction mixture was cooled down to room temperature and DME was removed under vacuum. The residue was partitioned between DCM/water. The DCM extracts were combined, dried over magnesium sulfate, then filtered and concentrated under vacuum. The crude residue was subjected to column chromatography on silica gel eluted with ethyl acetate/DCM 2/98 to 10/90 (v/v) gradient mixture. The pure fractions were combined and concentrated under vacuum yielding 8-(4-(3,4-bis(methyl-d3)phenyl)-5-methylpyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (5 g, 13.00 mmol, 64.8% yield)

Step 4

8-(4-(3,4-bis(methyl-d3)phenyl)-5-methylpyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (5 g, 13.00 mmol) was dissolved in 45 mL of tetrahydrofuran (THF). Dimethyl sulfoxide-d6 (40 ml, 571 mmol) was added by syringe into the reaction mixture. Sodium tert-butoxide (0.63 g, 6.56 mmol) was added as one portion to the reaction mixture. This mixture was degassed and heated at 65° C. for 17 hours, then cooled down to room temperature. The reaction mixture was quenched with 60 mL of D₂O and was stirred at room temperature for 45 minutes. This mixture was then diluted with 200 mL of water, then extracted with 3×70 mL DCM. These extracts were combined, dried over magnesium sulfate, then filtered and concentrated under vacuum, The crude residue was subjected to column chromatography on silica gel columns eluted with 1-3 vol-% THF/97-99 vol-% DCM. The resulting product fractions were combined and concentrated under vacuum yielding 4 g of product. This material was recrystallized from ethyl acetate several times yielding 8-(4-(3,4-bis(methyl-d3)phenyl)-5-(methyl-d3)pyridin-2-yl)-2-(methyl-d3)benzofuro[2,3-b]pyridine (2.1 g, 5.38 mmol, 41.4% yield).

Step 5

8-(4-(3,4-bis(methyl-d3)phenyl)-5-(methyl-d3)pyridin-2-yl)-2-(methyl-d3)benzofuro[2,3-b]pyridine (2.1 g, 5.38 mmol) was dissolved in 65 mL of ethanol. The “iridium salt” shown above (2.23 g, 2.98 mmol) was charged into the reaction mixture with 60 mL of methanol. This mixture was degassed with nitrogen then heated in an oil bath at 73° C. for 6 days. Heating was discontinued. The reaction was diluted with 50 mL of methanol, then filtered under vacuum. The resulting material was dried under vacuum, then dissolved in 400 mL of DCM before being passed through a plug of activated basic alumina. The DCM filtrate was concentrated under vacuum then passed through 7×120 g silica gel columns eluting the columns with 1st 90-99 vol-% toluene/1-10 vol-% heptanes and second with 1-2 vol-% ethyl acetate/98-99 vol-% toluene. Clean product fractions yielded the desired iridium complex (0.4 g, 0.433 mmol, 8.05% yield).

Synthesis of Compound 812773

Step 1

2,5-Dichloro-4-methylpyridine (7 g, 43.2 mmol), 2-methyl-8-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzofuro[2,3-b]pyridine (13.36 g, 43.2 mmol), and potassium carbonate (11.94 g, 86 mmol) were suspended in a mixture of DME (180 ml) and water (10 ml) under nitrogen at room temperature. Tetrakis(triphenylphosphine)palladium(0) (Pd(PPh₃)₄) (0.499 g, 0.432 mmol) was added as one portion, the reaction mixture was degassed and heated at 100° C. for 14 hours under nitrogen. The reaction mixture was then cooled down to room temperature and the organic phase was separated and filtered. Ethanol (100 ml) was added as one portion and the resulting mixture was stirred, then the white precipitate was filtered off. The remaining solution was evaporated and the residue was subjected to column chromatography on silica gel column, eluted with heptanes/DCM 1/1 (v/v), then heptanes/EtOAc 4/1 (v/v) to yield a white solid, which was combined with the white precipitate. The combined solids were recrystallyzed from DCM/heptanes, yielding 8-(5-chloro-4-methylpyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (11 g, 83% yield).

Step 2

8-(5-Chloro-4-methylpyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (11 g, 35.6 mmol), p-tolylboronic acid (5.81 g, 42.8 mmol), and potassium phosphate tribasic hydrate (16.41 g, 71.3 mmol) were suspended in the mixture of DME (150 ml) and water (5 ml) to give a colorless suspension. Pd₂(dba)₃ (0.326 g, 0.356 mmol) and dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane (Sphos, 0.293 g, 0.713 mmol) were added as one portion. The reaction mixture was degassed and heated at 100° C. for 14 hours under nitrogen. The reaction mixture was then cooled down to room temperature. The organic phase was separated, filtered, and evaporated. The residue was then subjected to column chromatography on silica gel, eluted with heptanes/THF 9/1 (v/v) gradient mixture, providing 2-methyl-8-(4-methyl-5-(p-tolyl)pyridin-2-yl)benzofuro[2,3-b]pyridine as a white solid (9.2 g, 71% yield).

Step 3

2-Methyl-8-(4-methyl-5-(p-toly)pyridin-2-yl)benzofuro[2,3-b]pyridine was dissolved in 55 g of DMSO-d6, then 1.2 of sodium tert-butoxide was added. The reaction mixture was degassed and stirred under nitrogen at 60° C. for 12 h. The reaction mixture was quenched with D₂O, diluted with water, and extracted with ethyl acetate. The organic solution was dried over sodium sulfate, filtered, and evaporated. The residue was subjected to column chromatography on silica gel, eluted with heptanes/THF 9/1 (v/v), providing 3.7 g of deuterated product with a 40% yield.

Step 4

2-(Methyl-d3)-8-(4-(methyl-d3)-5-(4-(methyl-d3)phenyl)pyridin-2-yl)benzofuro[2,3-b]pyridine (3.67 g, 9.83 mmol, 2.45 eq.) and the above iridium complex triflic salt were suspended in 50 ml of a 1/1 (v/v) mixture of ethanol and methanol. The reaction mixture was degassed and heated to reflux under nitrogen for 96 hour. Then, the reaction mixture was cooled to room temperature and a yellow solid precipitate was filtered off. Pure material was obtained by column chromatography on silica gel, eluted with toluene/heptanes 9/1 (v/v), followed by crystallyzation from toluene/heptanes and DCM/methanol, providing the target compound (1.1 g, 30% yield).

Device Examples

All example devices were fabricated by high vacuum (<10⁻⁷ Torr) thermal evaporation. The anode electrode was 750 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H₂O and O₂) immediately after fabrication with a moisture getter incorporated inside the package. The organic stack of the device examples consisted of sequentially, from the ITO surface: 100 Å of HAT-CN as the hole injection layer (HIL); 450 Å of HTM as a hole transporting layer (HTL); emissive layer (EML) with thickness 400 Å. Emissive layer containing H-host (H1): E-host (H2) in a 6:4 weight ratio and 12 weight % of green emitter. 350 Å of Liq (8-hydroxyquinoline lithium) doped with 40% of ETM as the ETL. Device structure is shown in the Table 1.

TABLE 1 schematic device structure Layer Material Thickness [Å] Anode ITO 750 HIL HAT-CN 100 HTL HTM 450 Green H1:H2: example 400 EML dopant ETL Liq:ETM 40% 350 EIL Liq 10 Cathode A1 1,000

Table 1 shows the schematic device structure. The chemical structures of the materials used in the device examples are shown below.

Upon fabrication, the devices are tested for EL, JVL and lifetime at DC 80 mA/cm². LT₉₅ at 1,000 nits was calculated from 80 mA/cm² assuming an acceleration factor of 1.8. Device performance is shown in the Table 2

TABLE 2 Device performance 1931 CIE At 1,000 nits Emitter λ max FWHM Voltage LE EQE Relative LT 12% x y [nm] [nm] [V] [cd/A] [%] 95% [h] Compound 0.371 0.609 535 60 3.1 91 24 137 275205 Comparative 0.328 0.634 524 60 3.1 96 25 100 Example 1 Compound 0.352 0.623 530 61 3.0 105 27 85 812773 Comparative 0.337 0.631 526 60 3.1 94 24 146 Example 2

Comparing compound 275205 and the comparative example 1, the stability of compound 275205 in a device is much better than the comparative example 1. Presumably, the extend conjugation of the pyridine ring helps the electron stability and extends the device lifetime. Comparing compound 812773 and the comparative example 2, compound 812773 unexpectly has a higher efficiency than the comparative example 2 (27% eqe vs 24% eqe at 1000 nits). Overall, inclusion of a partially twist ary ring on the pyridine ring improve the life time and efficiency without red shifting the color significantly.

It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting. 

1. A compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n), having the structure:

wherein each of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is independently carbon or nitrogen; wherein at least one of A¹, A², A³, A⁴, A³, A⁶, A⁷, and A⁸ is nitrogen; wherein ring B is bonded to ring A through a C—C bond: wherein the iridium is bonded to ring A through an Ir—C bond; wherein X is O, S, or Se; wherein R¹, R², R³, R⁴, and R⁵ independently represent from mono-substituted to the maximum possibly substitutions, or no substitution; wherein any adjacent substitutions in R¹, R², R³, R⁴, and R³ are optionally linked together to form a ring; wherein R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrite, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein n is an integer from 1 to 3; and wherein at least one R² adjacent to ring C is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variations thereof, partially or fully fluorinated variations thereof, and combinations thereof.
 2. The compound of claim 1, wherein n is
 1. 3. The compound of claim 1, wherein the compound is selected from the group consisting of:


4. The compound of claim 1, wherein only one of A¹ to A⁸ is nitrogen.
 5. The compound of claim 1, wherein A¹ to A⁴ are carbon, and exactly one of A⁵ to A⁸ is nitrogen.
 6. The compound of claim 1, wherein X is O.
 7. The compound of claim 1, wherein R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, partial fluorinated alkyl, partial fluorinated cycloalkyl, and combinations thereof.
 8. The compound of claim 3, wherein the compound is selected from the group consisting of:


9. The compound of claim 8, wherein R′ next to N is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variants thereof, partially fluorinated variants thereof, and combinations thereof.
 10. The compound of claim 1, wherein L_(A) is selected from the group consisting of L_(Ap,1) to L_(Ap,634) and L_(Am,1) to L_(Am,634), where L_(Ap,i) and L_(Am,i) have structures

wherein i is an integer from 1 to 634, and the corresponding substituents R^(A1), R^(A2), R^(A3), and R^(A4) are defined as follows: i R^(A1) R^(A2) R^(A3) R^(A4)
 1. CH₃ H H H
 2. CH₃ CH₃ H CH₃
 3. CH₃ H CH₃ H
 4. CH₃ H H CH₃
 5. CH₃ CH₃ CH₃ H
 6. CH₃ CH₃ H CH₃
 7. CH₃ H CH₃ CH₃
 8. CH₃ CH₃ CH₃ CH₃
 9. CH₂CH₃ H H H
 10. CH₂CH₃ CH₃ H CH₃
 11. CH₂CH₃ H CH₃ H
 12. CH₂CH₃ H H CH₃
 13. CH₂CH₃ CH₃ CH₃ H
 14. CH₂CH₃ CH₃ H CH₃
 15. CH₂CH₃ H CH₃ CH₃
 16. CH₂CH₃ CH₃ CH₃ CH₃
 17. CH₃ CH₂CH₃ H CH₃
 18. CH₃ CH₂CH₃ CH₃ H
 19. CH₃ CH₂CH₃ H CH₃
 20. CH₃ CH₂CH₃ CH₃ CH₃
 21. CH₃ H CH₂CH₃ H
 22. CH₃ CH₃ CH₂CH₃ H
 23. CH₃ H CH₂CH₃ CH₃
 24. CH₃ CH₃ CH₂CH₃ CH₃
 25. CH(CH₃)₂ H H H
 26. CH(CH₃)₂ CH₃ H CH₃
 27. CH(CH₃)₂ H CH₃ H
 28. CH(CH₃)₂ H H CH₃
 29. CH(CH₃)₂ CH₃ CH₃ H
 30. CH(CH₃)₂ CH₃ H CH₃
 31. CH(CH₃)₂ H CH₃ CH₃
 32. CH(CH₃)₂ CH₃ CH₃ CH₃
 33. CH₃ CH(CH₃)₂ H CH₃
 34. CH₃ CH(CH₃)₂ CH₃ H
 35. CH₃ CH(CH₃)₂ H CH₃ 36 CH₃ CH(CH₃)₂ CH₃ CH₃
 37. CH₃ H CH(CH₃)₂ H
 38. CH₃ CH₃ CH(CH₃)₂ H
 39. CH₃ H CH(CH₃)₂ CH₃
 40. CH₃ CH₃ CH(CH₃)₂ CH₃
 41. CH₂CH(CH₃)₂ H H H
 42. CH₂CH(CH₃)₂ CH₃ H CH₃
 43. CH₂CH(CH₃)₂ H CH₃ H
 44. CH₂CH(CH₃)₂ H H CH₃
 45. CH₂CH(CH₃)₂ CH₃ CH₃ H
 46. CH₂CH(CH₃)₂ CH₃ H CH₃
 47. CH₂CH(CH₃)₂ H CH₃ CH₃
 48. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃
 49. CH₃ CH₂CH(CH₃)₂ H CH₃
 50. CH₃ CH₂CH(CH₃)₂ CH₃ H
 51. CH₃ CH₂CH(CH₃)₂ H CH₃
 52. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃
 53. CH₃ H CH₂CH(CH₃)₂ H
 54. CH₃ CH₃ CH₂CH(CH₃)₂ H
 55. CH₃ H CH₂CH(CH₃)₂ CH₃
 56. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃
 57. C(CH₃)₃ H H H
 58. C(CH₃)₃ CH₃ H CH₃
 59. C(CH₃)₃ H CH₃ H
 60. C(CH₃)₃ H H CH₃
 61. C(CH₃)₃ CH₃ CH₃ H
 62. C(CH₃)₃ CH₃ H CH₃
 63. C(CH₃)₃ H CH₃ CH₃
 64. C(CH₃)₃ CH₃ CH₃ CH₃
 65. CH₃ C(CH₃)₃ H CH₃
 66. CH₃ C(CH₃)₃ CH₃ H
 67. CH₃ C(CH₃)₃ H CH₃
 68. CH₃ C(CH₃)₃ CH₃ CH₃
 69. CH₃ H C(CH₃)₃ H
 70. CH₃ CH₃ C(CH₃)₃ H
 71. CH₃ H C(CH₃)₃ CH₃
 72. CH₃ CH₃ C(CH₃)₃ CH₃
 73. CH₂C(CH₃)₃ H H H
 74. CH₂C(CH₃)₃ CH₃ H CH₃
 75. CH₂C(CH₃)₃ H CH₃ H
 76. CH₂C(CH₃)₃ H H CH₃
 77. CH₂C(CH₃)₃ CH₃ CH₃ H
 78. CH₂C(CH₃)₃ CH₃ H CH₃
 79. CH₂C(CH₃)₃ H CH₃ CH₃
 80. CH₂C(CH₃)₃ CH₃ CH₃ CH₃
 81. CH₃ CH₂C(CH₃)₃ H CH₃
 82. CH₃ CH₂C(CH₃)₃ CH₃ H
 83. CH₃ CH₂C(CH₃)₃ H CH₃
 84. CH₃ CH₂C(CH₃)₃ CH₃ CH₃
 85. CH₃ H CH₂C(CH₃)₃ H
 86. CH₃ CH₃ CH₂C(CH₃)₃ H
 87. CH₃ H CH₂C(CH₃)₃ CH₃
 88. CH₃ CH₃ CH₂C(CH₃)₃ CH₃
 89. CH₂C(CH₃)₂CF₃ H H H
 90. CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 91. CH₂C(CH₃)₂CF₃ H CH₃ H
 92. CH₂C(CH₃)₂CF₃ H H CH₃
 93. CH₂C(CH₃)₂CF₃ CH₃ CH₃ H
 94. CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 95. CH₂C(CH₃)₂CF₃ H CH₃ CH₃
 96. CH₂C(CH₃)₂CF₃ CH₃ CH₃ CH₃
 97. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 98. CH₃ CH₂C(CH₃)₂CF₃ CH₃ H
 99. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 100. CH₃ CH₂C(CH₃)₂CF₃ CH₃ CH₃
 101. CH₃ H CH₂C(CH₃)₂CF₃ H
 102. CH₃ CH₃ CH₂C(CH₃)₂CF₃ H
 103. CH₃ H CH₂C(CH₃)₂CF₃ CH₃
 104. CH₃ CH₃ CH₂C(CH₃)₂CF₃ CH₃
 105. CH₂CH₂CF₃ H H H
 106. CH₂CH₂CF₃ CH₃ H CH₃
 107. CH₂CH₂CF₃ H CH₃ H
 108. CH₂CH₂CF₃ H H CH₃
 109. CH₂CH₂CF₃ CH₃ CH₃ H
 110. CH₂CH₂CF₃ CH₃ H CH₃
 111. CH₂CH₂CF₃ H CH₃ CH₃
 112. CH₂CH₂CF₃ CH₃ CH₃ CH₃
 113. CH₃ CH₂CH₂CF₃ H CH₃
 114. CH₃ CH₂CH₂CF₃ CH₃ H
 115. CH₃ CH₂CH₂CF₃ H CH₃
 116. CH₃ CH₂CH₂CF₃ CH₃ CH₃
 117. CH₃ H CH₂CH₂CF₃ H
 118. CH₃ CH₃ CH₂CH₂CF₃ H
 119. CH₃ H CH₂CH₂CF₃ CH₃
 120. CH₃ CH₃ CH₂CH₂CF₃ CH₃
 121.

H H H
 122.

CH₃ H CH₃
 123.

H CH₃ H
 124.

H H CH₃
 125.

CH₃ CH₃ H
 126.

CH₃ H CH₃
 127.

H CH₃ CH₃
 128.

CH₃ CH₃ CH₃
 129. CH₃

H CH₃
 130. CH₃

CH₃ H
 131. CH₃

H CH₃
 132. CH₃

CH₃ CH₃
 133. CH₃ H

H
 134. CH₃ CH₃

H
 135. CH₃ H

CH₃
 136. CH₃ CH₃

CH₃
 137.

H H H
 138.

CH₃ H CH₃
 139.

H CH₃ H
 140.

H H CH₃
 141.

CH₃ CH₃ H
 142.

CH₃ H CH₃
 143.

H CH₃ CH₃
 144.

CH₃ CH₃ CH₃
 145. CH₃

H CH₃
 146. CH₃

CH₃ H
 147. CH₃

H CH₃
 148. CH₃

CH₃ CH₃
 149. CH₃ H

H
 150. CH₃ CH₃

H
 151. CH₃ H

CH₃
 152. CH₃ CH₃

CH₃
 153.

H H H
 154.

CH₃ H CH₃
 155.

H CH₃ H
 156.

H H CH₃
 157.

CH₃ CH₃ H
 158.

CH₃ H CH₃
 159.

H CH₃ CH₃
 160.

CH₃ CH₃ CH₃
 161. CH₃

H CH₃
 162. CH₃

CH₃ H
 163. CH₃

H CH₃
 164. CH₃

CH₃ CH₃
 165. CH₃ H

H
 166. CH₃ CH₃

H
 167. CH₃ H

CH₃
 168. CH₃ CH₃

CH₃
 169.

H H H
 170.

CH₃ H CH₃
 171.

H CH₃ H
 172.

H H CH₃
 173.

CH₃ CH₃ H
 174.

CH₃ H CH₃
 175.

H CH₃ CH₃
 176.

CH₃ CH₃ CH₃
 177. CH₃

H CH₃
 178. CH₃

CH₃ H
 179. CH₃

H CH₃
 180. CH₃

CH₃ CH₃
 181. CH₃ H

H
 182. CH₃ CH₃

H
 183. CH₃ H

CH₃
 184. CH₃ CH₃

CH₃
 185.

H H H
 186.

CH₃ H CH₃
 187.

H CH₃ H
 188.

H H CH₃
 189.

CH₃ CH₃ H
 190.

CH₃ H CH₃
 191.

H CH₃ CH₃
 192.

CH₃ CH₃ CH₃
 193. CH₃

H CH₃
 194. CH₃

CH₃ H
 195. CH₃

H CH₃
 196. CH₃

CH₃ CH₃
 197. CH₃ H

H
 198. CH₃ CH₃

H
 199. CH₃ H

CH₃
 200. CH₃ CH₃

CH₃
 201.

H H H
 202.

CH₃ H CH₃
 203.

H CH₃ H
 204.

H H CH₃
 205.

CH₃ CH₃ H
 206.

CH₃ H CH₃
 207.

H CH₃ CH₃ 208

CH₃ CH₃ CH₃
 209. CH₃

H CH₃
 210. CH₃

CH₃ H
 211. CH₃

H CH₃
 212. CH₃

CH₃ CH₃
 213. CH₃ H

H
 214. CH₃ CH₃

H
 215. CH₃ H

CH₃
 216. CH₃ CH₃

CH₃
 217. CH(CH₃)₂ H CH₂CH₃ H
 218. CH(CH₃)₂ H CH(CH₃)₂ H
 219. CH(CH₃)₂ H CH₂CH(CH₃)₂ H
 220. CH(CH₃)₂ H C(CH₃)₃ H
 221. CH(CH₃)₂ H CH₂C(CH₃)₃ H
 222. CH(CH₃)₂ H CH₂CH₂CF₃ H
 223. CH(CH₃)₂ H CH₂C(CH₃)₂CF₃ H
 224. CH(CH₃)₂ H

H
 225. CH(CH₃)₂ H

H
 226. CH(CH₃)₂ H

H
 227. CH(CH₃)₂ H

H
 228. CH(CH₃)₂ H

H
 229. CH(CH₃)₂ H

H
 230. C(CH₃)₃ H CH₂CH₃ H
 231. C(CH₃)₃ H CH(CH₃)₂ H
 232. C(CH₃)₃ H CH₂CH(CH₃)₂ H
 233. C(CH₃)₃ H C(CH₃)₃ H
 234. C(CH₃)₃ H CH₂C(CH₃)₃ H
 235. C(CH₃)₃ H CH₂CH₂CF₃ H
 236. C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 237. C(CH₃)₃ H

H
 238. C(CH₃)₃ H

H
 239. C(CH₃)₃ H

H
 240. C(CH₃)₃ H

H
 241. C(CH₃)₃ H

H
 242. C(CH₃)₃ H

H
 243. CH₂C(CH₃)₃ H CH₂CH₃ H
 244. CH₂C(CH₃)₃ H CH(CH₃)₂ H
 245. CH₂C(CH₃)₃ h CH₂Ch(CH₃)₂ H
 246. CH₂C(CH₃)₃ H C(CH₃)₃ H
 247. CH₂C(CH₃)₃ H CH₂(CH₃)₃ H
 248. CH₂C(CH₃)₃ H CH₂CH₂CF₃ H
 249. CH₂C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 250. CH₂C(CH₃)₃ H

H
 251. CH₂C(CH₃)₃ H

H
 252. CH₂C(CH₃)₃ H

H
 253. CH₂C(CH₃)₃ H

H
 254. CH₂C(CH₃)₃ H

H
 255. CH₂C(CH₃)₃ H

H
 256.

H CH₂CH₃ H
 257.

H CH(CH₃)₂ H
 258.

H CH₂CH(CH₃)₂ H
 259.

H C(CH₃)₃ H
 260.

H CH₂C(CH₃)₃ H
 261.

H CH₂CH₂CF₃ H
 262.

H CH₂C(CH₃)₂CF₃ H
 263.

H

H
 264.

H

H
 265.

H

H
 266.

H

H
 267.

H

H
 268.

H

H
 269.

H CH₂CH₃ H
 270.

H CH(CH₃)₂ H
 271.

H CH₂CH(CH₃)₂ H
 272.

H C(CH₃)₃ H
 273.

H CH₂C(CH₃)₃ H
 274.

H CH₂CH₂CF₃ H
 275.

H CH₂C(CH₃)₂CF₃ H
 276.

H

H
 277.

H

H
 278.

H

H
 279.

H

H
 280.

H

H
 281.

H

H
 282.

H CH₂CH(CH₃)₂ H
 283.

H C(CH₃)₃ H
 284.

H CH₂C(CH₃)₃ H
 285.

H CH₂CH₂CF₃ H
 286.

H CH₂C(CH₃)₂CF₃ H
 287.

H

H
 288.

H

H
 289.

H

H
 290.

H

H
 291.

H

H
 292.

H

H
 293.

H CH₂CH(CH₃)₂ H
 294.

H C(CH₃)₃ H
 295.

H CH₂C(CH₃)₃ H
 296.

H CH₂CH₂CF₃ H
 297.

H CH₂C(CH₃)₂CF₃ H
 298.

H

H
 299.

H

H
 300.

H

H
 301.

H

H
 302.

H

H
 303.

H

H
 304.

H CH₂CH(CH₃)₂ H
 305.

H C(CH₃)₃ H
 306.

H CH₂C(CH₃)₃ H
 307.

H CH₂CH₂CF₃ H
 308.

H CH₂C(CH₃)₂CF₃ H
 309.

H

H
 310.

H

H
 311.

H

H
 312.

H

H
 313.

H

H
 314.

H

H
 315. CD₃ H H H
 316. CD₃ CD₃ H CD₃
 317. CD₃ H CD₃ H
 318. CD₃ H H CD₃
 319. CD₃ CD₃ CD₃ H
 320. CD₃ CD₃ H CD₃
 321. CD₃ H CD₃ CD₃
 322. CD₃ CD₃ CD₃ CD₃
 323. CD₂CH₃ H H H
 324. CD₂CH₃ CD₃ H CD₃
 325. CD₂CH₃ H CD₃ H
 326. CD₂CH₃ H H CD₃
 327. CD₂CH₃ CD₃ CD₃ H
 328. CD₂CH₃ CD₃ H CD₃
 329. CD₂CH₃ H CD₃ CD₃
 330. CD₂CH₃ CD₃ CD₃ CD₃
 331. CH₃ CD₂CH₃ H CD₃
 332. CD₃ CD₂CH₃ CD₃ H
 333. CD₃ CD₂CH₃ H CD₃
 334. CD₃ CD₂CH₃ CD₃ CD₃
 335. CD₃ H CD₂CH₃ H
 336. CD₃ CD₃ CD₂CH₃ H
 337. CD₃ H CD₂CH₃ CD₃
 338. CD₃ CD₃ CD₂CH₃ CD₃
 339. CD(CH₃)₂ H H H
 340. CD(CH₃)₂ CD₃ H CD₃
 341. CD(CH₃)₂ H CD₃ H
 342. CD(CH₃)₂ H H CD₃
 343. CD(CH₃)₂ CD₃ CD₃ H
 344. CD(CH₃)₂ CD₃ H CD₃
 345. CD(CH₃)₂ H CD₃ CD₃
 346. CD(CH₃)₂ CD₃ CD₃ CD₃
 347. CD₃ CD(CH₃)₂ H CD₃
 348. CD₃ CD(CH₃)₂ CD₃ H
 349. CD₃ CD(CH₃)₂ H CD₃
 350. CD₃ CD(CH₃)₂ CD₃ CD₃
 351. CD₃ H CD(CH₃)₂ H
 352. CD₃ CD₃ CD(CH₃)₂ H
 353. CD₃ H CD(CH₃)₂ CD₃
 354. CD₃ CD₃ CD(CH₃)₂ CD₃
 355. CD(CD₃)₂ H H H
 356. CD(CD₃)₂ CD₃ H CD₃
 357. CD(CD₃)₂ H CD₃ H
 358. CD(CD₃)₂ H H CD₃
 359. CD(CD₃)₂ CD₃ CD₃ H
 360. CD(CD₃)₂ CD₃ H CD₃
 361. CD(CD₃)₂ H CD₃ CD₃
 362. CD(CD₃)₂ CD₃ CD₃ CD₃
 363. CH₃ CD(CD₃)₂ H CD₃
 364. CD₃ CD(CD₃)₂ CD₃ H
 365. CD₃ CD(CD₃)₂ H CD₃
 366. CD₃ CD(CD₃)₂ CD₃ CD₃
 367. CD₃ H CD(CD₃)₂ H
 368. CD₃ CD₃ CD(CD₃)₂ H
 369. CD₃ H CD(CD₃)₂ CD₃
 370. CD₃ CD₃ CD(CD₃)₂ CD₃
 371. CD₂CH(CH₃)₂ H H H
 372. CD₂CH(CH₃)₂ CD₃ H CD₃
 373. CD₂CH(CH₃)₂ H CD₃ H
 374. CD₂CH(CH₃)₂ H H CD₃
 375. CD₂CH(CH₃)₂ CD₃ CD₃ H
 376. CD₂CH(CH₃)₂ CD₃ H CD₃
 377. CD₂CH(CH₃)₂ H CD₃ CD₃
 378. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃
 379. CD₃ CD₂CH(CH₃)₂ H CD₃
 380. CD₃ CD₂CH(CH₃)₂ CD₃ H
 381. CD₃ CD₂CH(CH₃)₂ H CD₃
 382. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 383. CD₃ H CD₂CH(CH₃)₂ H
 384. CD₃ CD₃ CD₂CH(CH₃)₂ H
 385. CD₃ H CD₂CH(CH₃)₂ CD₃
 386. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃
 387. CD₂C(CH₃)₃ H H H
 388. CD₂C(CH₃)₃ CD₃ H CD₃
 389. CD₂C(CH₃)₃ H CD₃ H
 390. CD₂C(CH₃)₃ H H CD₃
 391. CD₂C(CH₃)₃ CD₃ CD₃ H
 392. CD₂C(CH₃)₃ CD₃ H CD₃
 393. CD₂C(CH₃)₃ H CD₃ CD₃
 394. CD₂C(CH₃)₃ CH₃ CD₃ CD₃
 395. CD₃ CD₂C(CH₃)₃ H CD₃
 396. CD₃ CD₂C(CH₃)₃ CD₃ H
 397. CD₃ CD₂C(CH₃)₃ H CD₃
 398. CD₃ CD₂C(CH₃)₃ CD₃ CD₃
 399. CD₃ H CD₂C(CH₃)₃ H
 400. CD₃ CD₃ CD₂C(CH₃)₃ H
 401. CD₃ H CD₂C(CH₃)₃ CD₃
 402. CD₃ CD₃ CD₂C(CH₃)₃ CD₃
 403. CD₂C(CH₃)₂CF₃ H H H
 404. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 405. CD₂C(CH₃)₂CF₃ H CD₃ H
 406. CD₂C(CH₃)₂CF₃ H H CD₃
 407. CD₂C(CH₃)₂CF₃ CD₃ CD₃ H
 408. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 409. CD₂C(CH₃)₂CF₃ H CD₃ CD₃
 410. CD₂C(CH₃)₂CF₃ CD₃ CD₃ CD₃
 411. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 412. CD₃ CD₂C(CH₃)₂CF₃ CD₃ H
 413. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 414. CD₃ CD₂C(CH₃)₂CF₃ CD₃ CD₃
 415. CD₃ H CD₂C(CH₃)₂CF₃ H
 416. CD₃ CD₃ CD₂C(CH₃)₂CF₃ H
 417. CD₃ H CD₂C(CH₃)₂CF₃ CD₃
 418. CD₃ CD₃ CD₂C(CH₃)₂CF₃ CD₃
 419. CD₂CH₂CF₃ H H H
 420. CD₂CH₂CF₃ CD₃ H CD₃
 421. CD₂CH₂CF₃ H CD₃ H
 422. CD₂CH₂CF₃ CD₃ CD₃ H
 423. CD₂CH₂CF₃ CD₃ CD₃ H
 424. CD₂CH₂CF₃ CD₃ H CD₃
 425. CD₂CH₂CF₃ H CD₃ CD₃
 426. CD₂CH₂CF₃ CD₃ CD₃ CD₃
 427. CD₃ CD₂CH₂CF₃ H CD₃
 428. CD₃ CD₂CH₂CF₃ CD₃ H
 429. CD₃ CD₂CH₂CF₃ H CD₃
 430. CD₃ CD₂CH₂CF₃ CD₃ CD₃
 431. CD₃ H CD₂CH₂CF₃ H
 432. CD₃ CD₃ CD₂CH₂CF₃ H
 433. CD₃ H CD₂CH₂CF₃ CD₃
 434. CD₃ CD₃ CD₂CH₂CF₃ CD₃
 435.

H H H
 436.

CD₃ H CD₃
 437.

H CD₃ H
 438.

H H CD₃
 439.

CD₃ CD₃ H
 440.

CD₃ H CD₃
 441.

H CD₃ CD₃
 442.

CD₃ CD₃ CD₃
 443. CD₃

H CD₃
 444. CD₃

CD₃ H
 445. CD₃

H CD₃
 446. CD₃

CD₃ CD₃
 447. CD₃ H

H
 448. CD₃ CD₃

H
 449. CD₃ H

CD₃
 450. CD₃ CD₃

CD₃
 451.

H H H
 452.

CD₃ H CD₃
 453.

H CD₃ H
 454.

H H CD₃
 455.

CD₃ CD₃ H
 456.

CD₃ H CD₃
 457.

H CD₃ CD₃
 458.

CD₃ CD₃ CD₃
 459. CH₃

H CD₃
 460. CD₃

CD₃ H
 461. CD₃

H CD₃
 462. CH₃

CD₃ CD₃
 485.

H CD₃ H
 486.

H H CD₃
 487.

CD₃ CD₃ H
 488.

CD₃ H CD₃
 489.

H CD₃ CD₃
 490.

CD₃ CD₃ CD₃
 491. CD₃

H CD₃
 492. CD₃

CD₃ H
 493. CD₃

H CD₃
 494. CD₃

CD₃ CD₃
 495. CD₃ H

H
 496. CD₃ CD₃

H
 497. CD₃ H

CD₃
 498. CD₃ CD₃

CD₃
 499.

H H H
 500.

CD₃ H CD₃
 501.

H CD₃ H
 502.

H H CD₃
 503.

CD₃ CD₃ H
 504.

CD₃ H CD₃
 505.

H CD₃ CD₃
 463. CD₃ H

H
 464. CD₃ CD₃

H
 465. CD₃ H

CD₃
 466. CD₃ CD₃

CD₃
 467.

H H H
 468.

CD₃ H CD₃
 469.

H CD₃ H
 470.

H H CD₃
 471.

CD₃ CD₃ H
 472.

CD₃ H CD₃
 473.

H CD₃ CD₃
 474.

CD₃ CD₃ CD₃
 475. CD₃

H CD₃
 476. CD₃

CD₃ H
 477. CD₃

H CD₃
 478. CD₃

CD₃ CD₃
 479. CD₃ H

H
 480. CD₃ CD₃

H
 481. CD₃ H

CD₃
 482. CD₃ CD₃

CD₃
 483.

H H H
 484.

CD₃ H CD₃
 506.

CD₃ CD₃ CD₃
 507. CD₃

H CD₃
 508. CD₃

CD₃ H
 509. CD₃

H CD₃
 510. CD₃

CD₃ CD₃
 511. CD₃ H

H
 512. CD₃ CD₃

H
 513. CD₃ H

CD₃
 514. CD₃ CD₃

CD₃
 515.

H H H
 516.

CD₃ H CD₃
 517.

H CD₃ H
 518.

H H CD₃
 519.

CH₃ CH₃ H
 520.

CD₃ H CD₃
 521.

H CD₃ CD₃
 522.

CD₃ CD₃ CD₃
 523. CD₃

H CD₃
 524. CD₃

CD₃ H
 525. CD₃

H CD₃
 526. CD₃

CD₃ CD₃
 527. CD₃ H

H
 528. CD₃ CD₃

H
 529. CD₃ H

CD₃
 530. CD₃ CD₃

CD₃
 531. CD(CH₃)₂ H CD₂CH₃ H
 532. CD(CH₃)₂ H CD(CH₃)₂ H
 533. CD(CH₃)₂ H CD₂CH(CH₃)₂ H
 534. CD(CH₃)₂ H C(CH₃)₃ H
 535. CD(CH₃)₂ H CD₂C(CH₃)₃ H
 536. CD(CH₃)₂ H CD₂CH₂CF₃ H
 537. CD(CH₃)₂ H CD₂C(CH₃)₂CF₃ H
 538. CD(CH₃)₂ H

H
 539. CD(CH₃)₂ H

H
 540. CD(CH₃)₂ H

H
 541. CD(CH₃)₂ H

H
 542. CD(CH₃)₂ H

H
 543. CD(CH₃)₂ H

H
 544. C(CH₃)₃ H CD₂CH₃ H
 545. C(CH₃)₃ H CD(CH₃)₂ H
 546. C(CH₃)₃ H CD₂CH(CH₃)₂ H
 547. C(CH₃)₃ H C(CH₃)₃ H
 548. C(CH₃)₃ H CD₂C(CH₃)₃ H
 549. C(CH₃)₃ H CD₂CH₂CF₃ H
 550. C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 551. C(CH₃)₃ H

H
 552. C(CH₃)₃ H

H
 553. C(CH₃)₃ H

H
 554. C(CH₃)₃ H

H
 555. C(CH₃)₃ H

H
 556. C(CH₃)₃ H

H
 557. CD₂C(CH₃)₃ H CD₂CH₃ H
 558. CD₂C(CH₃)₃ H CD(CH₃)₂ H
 559. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H
 560. CD₂C(CH₃)₃ H C(CH₃)₃ H
 561. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H
 562. CD₂C(CH₃)₃ H CD₂CH₂CF₃ H
 563. CD₂C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 564. CD₂C(CH₃)₃ H

H
 565. CD₂C(CH₃)₃ H

H
 566. CD₂C(CH₃)₃ H

H
 567. CD₂C(CH₃)₃ H

H
 568. CD₂C(CH₃)₃ H

H
 569. CD₂C(CH₃)₃ H

H
 570.

H CD₂CH₃ H
 571.

H CD(CH₃)₂ H
 572.

H CD₂CH(CH₃)₂ H
 573.

H C(CH₃)₃ H
 574.

H CD₂C(CH₃)₃ H
 575.

H CD₂CH₂CF₃ H
 576.

H CD₂C(CH₃)₂CF₃ H
 577.

H

H
 578.

H

H
 579.

H

H
 580.

H

H
 581.

H

H
 582.

H

H
 583.

H CD₂CH₃ H
 584.

H CD(CH₃)₂ H
 585.

H CD₂CH(CH₃)₂ H
 586.

H C(CH₃)₃ H
 587.

H CD₂C(CH₃)₃ H
 588.

H CD₂CH₂CF₃ H
 589.

H CD₂C(CH₃)₂CF₃ H
 590.

H

H
 591.

H

H
 592.

H

H
 593.

H

H
 594.

H

H
 595.

H

H
 596.

H CD₂CH₃ H
 597.

H CD(CH₃)₂ H
 598.

H CD₂CH(CH₃)₂ H
 599.

H C(CH₃)₃ H
 600.

H CD₂C(CH₃)₃ H
 601.

H CD₂CH₂CF₃ H
 602.

H CD₂C(CH₃)₂CF₃ H
 603.

H

H
 604.

H

H
 605.

H

H
 606.

H

H
 607.

H

H
 608.

H

H
 609.

H CD₂CH₃ H
 610.

H CD(CH₃)₂ H
 611.

H CD₂CH(CH₃)₂ H
 612.

H C(CH₃)₃ H
 613.

H CD₂C(CH₃)₃ H
 614.

H CD₂CH₂CF₃ H
 615.

H CD₂C(CH₃)₂CF₃ H
 616.

H

H
 617.

H

H
 618.

H

H
 619.

H

H
 620.

H

H
 621.

H

H
 622.

H CD₂CH₃ H
 623.

H CD(CH₃)₂ H
 624.

H CD₂CH(CH₃)₂ H
 625.

H C(CH₃)₃ H
 626.

H CD₂C(CH₃)₃ H
 627.

H CD₂CH₂CF₃ H
 628.

H CD₂C(CH₃)₂CF₃ H
 629.

H

H
 630.

H

H
 631.

H

H
 632.

H

H
 633.

H

H
 634.

H

H


11. The compound of claim 1, wherein L_(B) is selected from the group consisting of L_(B1) to L_(B855) defined by the structure L_(B,b):

wherein b is an integer from 1 to 855, and the corresponding substituents R^(B1), R^(B2), R^(B3), and R^(B4) are defined as follows: b R^(B1) R^(B2) R^(B3) R^(B4)
 1. H H H H
 2. CH₃ H H H
 3. H CH₃ H H
 4. H H CH₃ H
 5. CH₃ CH₃ H CH₃
 6. CH₃ H CH₃ H
 7. CH₃ H H CH₃
 8. H CH₃ CH₃ H
 9. H CH₃ H CH₃
 10. H H CH₃ CH₃
 11. CH₃ CH₃ CH₃ H
 12. CH₃ CH₃ H CH₃
 13. CH₃ H CH₃ CH₃
 14. H CH₃ CH₃ CH₃
 15. CH₃ CH₃ CH₃ CH₃
 16. CH₂CH₃ H H H
 17. CH₂CH₃ CH₃ H CH₃
 18. CH₂CH₃ H CH₃ H
 19. CH₂CH₃ H H CH₃
 20. CH₂CH₃ CH₃ CH₃ H
 21. CH₂CH₃ CH₃ H CH₃
 22. CH₂CH₃ H CH₃ CH₃
 23. CH₂CH₃ CH₃ CH₃ CH₃
 24. H CH₂CH₃ H H
 25. CH₃ CH₂CH₃ H CH₃
 26. H CH₂CH₃ CH₃ H
 27. H CH₂CH₃ H CH₃
 28. CH₃ CH₂CH₃ CH₃ H
 29. CH₃ CH₂CH₃ H CH₃
 30. H CH₂CH₃ CH₃ CH₃
 31. CH₃ CH₂CH₃ CH₃ CH₃
 32. H H CH₂CH₃ H
 33. CH₃ H CH₂CH₃ H
 34. H CH₃ CH₂CH₃ H
 35. H H CH₂CH₃ CH₃
 36. CH₃ CH₃ CH₂CH₃ H
 37. CH₃ H CH₂CH₃ CH₃
 38. H CH₃ CH₂CH₃ CH₃
 39. CH₃ CH₃ CH₂CH₃ CH₃
 40. CH(CH₃)₂ H H H
 41. CH(CH₃)₂ CH₃ H CH₃
 42. CH(CH₃)₂ H CH₃ H
 43. CH(CH₃)₂ H H CH₃
 44. CH(CH₃)₂ CH₃ CH₃ H
 45. CH(CH₃)₂ CH₃ H CH₃
 46. CH(CH₃)₂ H CH₃ CH₃
 47. CH(CH₃)₂ CH₃ CH₃ CH₃
 48. H CH(CH₃)₂ H H
 49. CH₃ CH(CH₃)₂ H CH₃
 50. H CH(CH₃)₂ CH₃ H
 51. H CH(CH₃)₂ H CH₃
 52. CH₃ CH(CH₃)₂ CH₃ H
 53. CH₃ CH(CH₃)₂ H CH₃
 54. H CH(CH₃)₂ CH₃ CH₃
 55. CH₃ CH(CH₃)₂ CH₃ CH₃
 56. H H CH(CH₃)₂ H
 57. CH₃ H CH(CH₃)₂ H
 58. H CH₃ CH(CH₃)₂ H
 59. H H CH(CH₃)₂ CH₃
 60. CH₃ CH₃ CH(CH₃)₂ H
 61. CH₃ H CH(CH₃)₂ CH₃
 62. H CH₃ CH(CH₃)₂ CH₃
 63. CH₃ CH₃ CH(CH₃)₂ CH₃
 64. CH₂CH(CH₃)₂ H H H
 65. CH₂CH(CH₃)₂ CH₃ H CH₃
 66. CH₂CH(CH₃)₂ H CH₃ H
 67. CH₂CH(CH₃)₂ H H CH₃
 68. CH₂CH(CH₃)₂ CH₃ CH₃ H
 69. CH₂CH(CH₃)₂ CH₃ H CH₃
 70. CH₂CH(CH₃)₂ H CH₃ CH₃
 71. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃
 72. H CH₂CH(CH₃)₂ H H
 73. CH₃ CH₂CH(CH₃)₂ H CH₃
 74. H CH₂CH(CH₃)₂ CH₃ H
 75. H CH₂CH(CH₃)₂ H CH₃
 76. CH₃ CH₂CH(CH₃)₂ CH₃ H
 77. CH₃ CH₂CH(CH₃)₂ H CH₃
 78. H CH₂CH(CH₃)₂ CH₃ CH₃
 79. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃
 80. H H CH₂CH(CH₃)₂ H
 81. CH₃ H CH₂CH(CH₃)₂ H
 82. H CH₃ CH₂CH(CH₃)₂ H
 83. H H CH₂CH(CH₃)₂ CH₃
 84. CH₃ CH₃ CH₂CH(CH₃)₂ H
 85. CH₃ H CH₂CH(CH₃)₂ CH₃
 86. H CH₃ CH₂CH(CH₃)₂ CH₃
 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃
 88. C(CH₃)₃ H H H
 89. C(CH₃)₃ CH₃ H CH₃
 90. C(CH₃)₃ H CH₃ H
 91. C(CH₃)₃ H H CH₃
 92. C(CH₃)₃ CH₃ CH₃ H
 93. C(CH₃)₃ CH₃ H CH₃
 94. C(CH₃)₃ H CH₃ CH₃
 95. C(CH₃)₃ CH₃ CH₃ CH₃
 96. H C(CH₃)₃ H H
 97. CH₃ C(CH₃)₃ H CH₃
 98. H C(CH₃)₃ CH₃ H
 99. H C(CH₃)₃ H CH₃
 100. CH₃ C(CH₃)₃ CH₃ H
 101. CH₃ C(CH₃)₃ H CH₃
 102. H C(CH₃)₃ CH₃ CH₃
 103. CH₃ C(CH₃)₃ CH₃ CH₃
 104. H H C(CH₃)₃ H
 105. CH₃ H C(CH₃)₃ H
 106. H CH₃ C(CH₃)₃ H
 107. H H C(CH₃)₃ CH₃
 108. CH₃ CH₃ C(CH₃)₃ H
 109. CH₃ H C(CH₃)₃ CH₃
 110. H CH₃ C(CH₃)₃ CH₃
 111. CH₃ CH₃ C(CH₃)₃ CH₃
 112. CH₂C(CH₃)₃ H H H
 113. CH₂C(CH₃)₃ CH₃ H CH₃
 114. CH₂C(CH₃)₃ H CH₃ H
 115. CH₂C(CH₃)₃ H H CH₃
 116. CH₂C(CH₃)₃ CH₃ CH₃ H
 117. CH₂C(CH₃)₃ CH₃ H CH₃
 118. CH₂C(CH₃)₃ H CH₃ CH₃
 119. CH₂C(CH₃)₃ CH₃ CH₃ CH₃
 120. H CH₂C(CH₃)₃ H H
 121. CH₃ CH₂C(CH₃)₃ H CH₃
 122. H CH₂C(CH₃)₃ CH₃ H
 123. H CH₂C(CH₃)₃ H CH₃
 124. CH₃ CH₂C(CH₃)₃ CH₃ H
 125. CH₃ CH₂C(CH₃)₃ H CH₃
 126. H CH₂C(CH₃)₃ CH₃ CH₃
 127. CH₃ CH₂C(CH₃)₃ CH₃ CH₃
 128. H H CH₂C(CH₃)₃ H
 129. CH₃ H CH₂C(CH₃)₃ H
 130. H CH₃ CH₂C(CH₃)₃ H
 131. H H CH₂C(CH₃)₃ CH₃
 132. CH₃ CH₃ CH₂C(CH₃)₃ H
 133. CH₃ H CH₂C(CH₃)₃ CH₃
 134. H CH₃ CH₂C(CH₃)₃ CH₃
 135. CH₃ CH₃ CH₂C(CH₃)₃ CH₃
 136. CH₂C(CH₃)₂CF₃ H H H
 137. CH₂C(CH₃)₂CF₃ H CH₃ H
 138. CH₂C(CH₃)₂CF₃ H CH₃ H
 139. CH₂C(CH₃)₂CF₃ H H CH₃
 140. CH₂C(CH₃)₂CF₃ CH₃ CH₃ H
 141. CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 142. CH₂C(CH₃)₂CF₃ H CH₃ CH₃
 143. CH₂C(CH₃)₂CF₃ CH₃ CH₃ CH₃
 144. H CH₂C(CH₃)₂CF₃ H H
 145. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 146. H CH₂C(CH₃)₂CF₃ CH₃ H
 147. H CH₂C(CH₃)₂CF₃ H CH₃
 148. CH₃ CH₂C(CH₃)₂CF₃ CH₃ H
 149. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 150. H CH₂C(CH₃)₂CF₃ CH₃ CH₃
 151. CH₃ CH₂C(CH₃)₂CF₃ CH₃ CH₃
 152. H H CH₂C(CH₃)₂CF₃ H
 153. CH₃ H CH₂C(CH₃)₂CF₃ H
 154. H CH₃ CH₂C(CH₃)₂CF₃ H
 155. H H CH₂C(CH₃)₂CF₃ CH₃
 156. CH₃ CH₃ CH₂C(CH₃)₂CF₃ H
 157. CH₃ H CH₂C(CH₃)₂CF₃ CH₃
 158. H CH₃ CH₂C(CH₃)₂CF₃ CH₃
 159. CH₃ CH₃ CH₂C(CH₃)₂CF₃ CH₃
 160. CH₂CH₂CF₃ H H H
 161. CH₂CH₂CF₃ CH₃ H CH₃
 162. CH₂CH₂CF₃ H CH₃ H
 163. CH₂CH₂CF₃ H H CH₃
 164. CH₂CH₂CF₃ CH₃ CH₃ H
 165. CH₂CH₂CF₃ CH₃ H CH₃
 166. CH₂CH₂CF₃ H CH₃ CH₃
 167. CH₂CH₂CF₃ CH₃ CH₃ CH₃
 168. H CH₂CH₂CF₃ H H
 169. CH₃ CH₂CH₂CF₃ H CH₃
 170. H CH₂CH₂CF₃ CH₃ H
 171. H CH₂CH₂CF₃ H CH₃
 172. CH₃ CH₂CH₂CF₃ CH₃ H
 173. CH₃ CH₂CH₂CF₃ H CH₃
 174. H CH₂CH₂CF₃ CH₃ CH₃
 175. CH₃ CH₂CH₂CF₃ CH₃ CH₃
 176. H H CH₂CH₂CF₃ H
 177. CH₃ H CH₂CH₂CF₃ H
 178. H CH₃ CH₂CH₂CF₃ H
 179. H H CH₂CH₂CF₃ CH₃
 180. CH₃ CH₃ CH₂CH₂CF₃ H
 181. CH₃ H CH₂CH₂CF₃ CH₃
 182. H CH₃ CH₂CH₂CF₃ CH₃
 183. CH₃ CH₃ CH₂CH₂CF₃ CH₃
 184.

H H H
 185.

CH₃ H CH₃
 186.

H CH₃ H
 187.

H H CH₃
 188.

CH₃ CH₃ H
 189.

CH₃ H CH₃
 190.

H CH₃ CH₃
 191.

CH₃ CH₃ CH₃
 192. H

H H
 193. CH₃

H CH₃
 194. H

CH₃ H
 195. H

H CH₃
 196. CH₃

CH₃ H
 197. CH₃

H CH₃
 198. H

CH₃ CH₃
 199. CH₃

CH₃ CH₃
 200. H H

H
 201. CH₃ H

H
 202. H CH₃

H
 203. H H

CH₃
 204. CH₃ CH₃

H
 205. CH₃ H

CH₃
 206. H CH₃

CH₃
 207. CH₃ CH₃

CH₃
 208.

H H H
 209.

CH₃ H CH₃
 210.

H CH₃ H
 211.

H H CH₃
 212.

CH₃ CH₃ H
 213.

CH₃ H CH₃
 214.

H CH₃ CH₃
 215.

CH₃ CH₃ CH₃
 216. H

H H
 217. CH₃

H CH₃
 218. H

CH₃ H
 219. H

H CH₃
 220. CH₃

CH₃ H
 221. CH₃

H CH₃
 222. H

CH₃ CH₃
 223. CH₃

CH₃ CH₃
 224. H H

H
 225. CH₃ H

H
 226. H CH₃

H
 227. H H

CH₃
 228. CH₃ CH₃

H
 229. CH₃ H

CH₃
 230. H CH₃

CH₃
 231. CH₃ CH₃

CH₃
 232.

H H H
 233.

CH₃ H CH₃
 234.

H CH₃ H
 235.

H H CH₃
 236.

CH₃ CH₃ H
 237.

CH₃ H CH₃
 238.

H CH₃ CH₃
 239.

CH₃ CH₃ CH₃
 240. H

H H
 241. CH₃

H CH₃
 242. H

CH₃ H
 243. H

H CH₃
 244. CH₃

CH₃ H
 245. CH₃

H CH₃
 246. H

CH₃ CH₃
 247. CH₃

CH₃ CH₃
 248. H H

H
 249. CH₃ H

H
 250. H CH₃

H
 251. H H

CH₃
 252. CH₃ CH₃

H
 253. CH₃ H

CH₃
 254. H CH₃

CH₃
 255. CH₃ CH₃

CH₃
 256.

H H H
 257.

CH₃ H CH₃
 258.

H CH₃ H
 259.

H H CH₃
 260.

CH₃ CH₃ H
 261.

CH₃ H CH₃
 262.

H CH₃ CH₃
 263.

CH₃ CH₃ CH₃
 264. H

H H
 265. CH₃

H CH₃
 266. H

CH₃ H
 267. H

H CH₃
 268. CH₃

CH₃ H
 269. CH₃

H CH₃
 270. H

CH₃ CH₃
 271. CH₃

CH₃ CH₃
 272. H H

H
 273. CH₃ H

H
 274. H CH₃

H
 275. H H

CH₃
 276. CH₃ CH₃

H
 277. CH₃ H

CH₃
 278. H CH₃

CH₃
 279. CH₃ CH₃

CH₃
 280.

H H H
 281.

CH₃ H CH₃
 282.

H CH₃ H
 283.

H H CH₃
 284.

CH₃ CH₃ H
 285.

CH₃ H CH₃
 286.

H CH₃ CH₃
 287.

CH₃ CH₃ CH₃
 288. H

H H
 289. CH₃

H CH₃
 290. H

CH₃ H
 291. H

H CH₃
 292. CH₃

CH₃ H
 293. CH₃

H CH₃
 294. H

CH₃ CH₃
 295. CH₃

CH₃ CH₃
 296. H H

H
 297. CH₃ H

H
 298. H CH₃

H
 299. H H

CH₃
 300. CH₃ CH₃

H
 301. CH₃ H

CH₃
 302. H CH₃

CH₃
 303. CH₃ CH₃

CH₃
 304.

H H H
 305.

CH₃ H CH₃
 306.

H CH₃ H
 307.

H H CH₃
 308.

CH₃ CH₃ H
 309.

CH₃ H CH₃
 310.

H CH₃ CH₃
 311.

CH₃ CH₃ CH₃
 312. H

H H
 313. CH₃

H CH₃
 314. H

CH₃ H
 315. H

H CH₃
 316. CH₃

CH₃ H
 317. CH₃

H CH₃
 318. H

CH₃ CH₃
 319. CH₃

CH₃ CH₃
 320. H H

H
 321. CH₃ H

H
 322. H CH₃

H
 323. H H

CH₃
 324. CH₃ CH₃

H
 325. CH₃ H

CH₃
 326. H CH₃

CH₃
 327. CH₃ CH₃

CH₃
 328. CH(CH₃)₂ H CH₂CH₃ H
 329. CH(CH₃)₂ H CH(CH₃)₂ H
 330. CH(CH₃)₂ H CH₂CH(CH₃)₂ H
 331. CH(CH₃)₂ H C(CH₃)₃ H
 332. CH(CH₃)₂ H CH₂C(CH₃)₃ H
 333. CH(CH₃)₂ H CH₂CH₂CF₃ H
 334. CH(CH₃)₂ H CH₂C(CH₃)₂CF₃ H
 335. CH(CH₃)₂ H

H
 336. CH(CH₃)₂ H

H
 337. CH(CH₃)₂ H

H
 338. CH(CH₃)₂ H

H
 339. CH(CH₃)₂ H

H
 340. CH(CH₃)₂ H

H
 341. C(CH₃)₃ H CH₂CH₃ H
 342. C(CH₃)₃ H CH(CH₃)₂ H
 343. C(CH₃)₃ H CH₂CH(CH₃)₂ H
 344. C(CH₃)₃ H C(CH₃)₃ H
 345. C(CH₃)₃ H CH₂C(CH₃)₃ H
 346. C(CH₃)₃ H CH₂CH₂CF₃ H
 347. C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 348. C(CH₃)₃ H

H
 349. C(CH₃)₃ H

H
 350. C(CH₃)₃ H

H
 351. C(CH₃)₃ H

H
 352. C(CH₃)₃ H

H
 353. C(CH₃)₃ H

H
 354. CH₂C(CH₃)₃ H CH₂CH₃ H
 355. CH₂C(CH₃)₃ H CH(CH₃)₂ H
 356. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H
 357. CH₂C(CH₃)₃ H C(CH₃)₃ H
 358. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H
 359. CH₂C(CH₃)₃ H CH₂CH₂CF₃ H
 360. CH₂C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 361. CH₂C(CH₃)₃ H

H
 362. CH₂C(CH₃)₃ H

H
 363. CH₂C(CH₃)₃ H

H
 364. CH₂C(CH₃)₃ H

H
 365. CH₂C(CH₃)₃ H

H
 366. CH₂C(CH₃)₃ H

H
 367.

H CH₂CH₃ H
 368.

H CH(CH₃)₂ H
 369.

H CH₂CH(CH₃)₂ H
 370.

H C(CH₃)₃ H
 371.

H CH₂C(CH₃)₃ H
 372.

H CH₂CH₂CF₃ H
 373.

H CH₂C(CH₃)₂CF₃ H
 374.

H

H
 375.

H

H
 376.

H

H
 377.

H

H
 378.

H

H
 379.

H

H
 380.

H CH₂CH₃ H
 381.

H CH(CH₃)₂ H
 382.

H CH₂CH(CH₃)₂ H
 383.

H C(CH₃)₃ H
 384.

H CH₂C(CH₃)₃ H
 385.

H CH₂CH₂CF₃ H
 386.

H CH₂C(CH₃)₂CF₃ H
 387.

H

H
 388.

H

H
 389.

H

H
 390.

H

H
 391.

H

H
 392.

H

H
 393.

H CH₂CH(CH₃)₂ H
 394.

H C(CH₃)₃ H
 395.

H CH₂C(CH₃)₃ H
 396.

H CH₂CH₂CF₃ H
 397.

H CH₂C(CH₃)₂CF₃ H
 398.

H

H
 399.

H

H
 400.

H

H
 401.

H

H
 402.

H

H
 403.

H

H
 404.

H CH₂CH(CH₃)₂ H
 405.

H C(CH₃)₃ H
 406.

H CH₂C(CH₃)₃ H
 407.

H CH₂CH₂CF₃ H
 408.

H CH₂C(CH₃)₂CF₃ H
 409.

H

H
 410.

H

H
 411.

H

H
 412.

H

H
 413.

H

H
 414.

H

H
 415.

H CH₂CH(CH₃)₂ H
 416.

H C(CH₃)₃ H
 417.

H CH₂C(CH₃)₃ H
 418.

H CH₂CH₂CF₃ H
 419.

H CH₂C(CH₃)₂CF₃ H
 420.

H

H
 421.

H

H
 422.

H

H
 423.

H

H
 424.

H

H
 425.

H

H
 426. CD₃ H H H
 427. H CD₃ H H
 428. H H CD₃ H
 429. CD₃ CD₃ H CD₃
 430. CD₃ H CD₃ H
 431. CD₃ H H CD₃
 432. H CD₃ CH₃ H
 433. H CD₃ H CD₃
 434. H H CD₃ CD₃
 435. CD₃ CD₃ CD₃ H
 436. CD₃ CD₃ H CD₃
 437. CD₃ H CD₃ CD₃
 438. H CD₃ CD₃ CD₃
 439. CD₃ CD₃ CD₃ CD₃
 440. CD₂CH₃ H H H
 441. CD₂CH₃ CD₃ H CD₃
 442. CD₂CH₃ H CD₃ H
 443. CD₂CH₃ H H CD₃
 444. CD₂CH₃ CD₃ CD₃ H
 445. CD₂CH₃ CD₃ H CD₃
 446. CD₂CH₃ H CD₃ CD₃
 447. CD₂CH₃ CD₃ CD₃ CD₃
 448. H CD₂CH₃ H H
 449. CH₃ CD₂CH₃ H CD₃
 450. H CD₂CH₃ CD₃ H
 451. H CD₂CH₃ H CD₃
 452. CD₃ CD₂CH₃ CD₃ H
 453. CD₃ CD₂CH₃ H CD₃
 454. H CD₂CH₃ CD₃ CD₃
 455. CD₃ CD₂CH₃ CD₃ CD₃
 456. H H CD₂CH₃ H
 457. CD₃ H CD₂CH₃ H
 458. H CD₃ CD₂CH₃ H
 459. H H CD₂CH₃ CD₃
 460. CD₃ CD₃ CD₂CH₃ H
 461. CD₃ H CD₂CH₃ CD₃
 462. H CD₃ CD₂CH₃ CD₃
 463. CD₃ CD₃ CD₂CH₃ CD₃
 464. CD(CH₃)₂ H H H
 465. CD(CH₃)₂ CD₃ H CD₃
 466. CD(CH₃)₂ H CD₃ H
 467. CD(CH₃)₂ H H CD₃
 468. CD(CH₃)₂ CD₃ CD₃ H
 469. CD(CH₃)₂ CD₃ H CD₃
 470. CD(CH₃)₂ H CD₃ CD₃
 471. CD(CH₃)₂ CD₃ CD₃ CD₃
 472. H CD(CH₃)₂ H H
 473. CD₃ CD(CH₃)₂ H CD₃
 474. H CD(CH₃)₂ CD₃ H
 475. H CD(CH₃)₂ H CD₃
 476. CD₃ CD(CH₃)₂ CD₃ H
 477. CD₃ CD(CH₃)₂ H CD₃
 478. H CD(CH₃)₂ CD₃ CD₃
 479. CD₃ CD(CH₃)₂ CD₃ CD₃
 480. H H CD(CH₃)₂ CD₃
 481. CD₃ H CD(CH₃)₂ H
 482. H CD₃ CD(CH₃)₂ H
 483. H H CD(CH₃)₂ CD₃
 484. CD₃ CD₃ CD(CH₃)₂ H
 485. CD₃ H CD(CH₃)₂ CD₃
 486. H CD₃ CD(CH₃)₂ CD₃
 487. CD₃ CD₃ CD(CH₃)₂ CD₃
 488. CD(CD₃)₂ H H H
 489. CD(CD₃)₂ CD₃ H CD₃
 490. CD(CD₃)₂ H CD₃ H
 491. CD(CD₃)₂ H H CD₃
 492. CD(CD₃)₂ CD₃ CD₃ H
 493. CD(CD₃)₂ CD₃ H CD₃
 494. CD(CD₃)₂ H CD₃ CD₃
 495. CD(CD₃)₂ CD₃ CD₃ CD₃
 496. H CD(CD₃)₂ H H
 497. CH₃ CD(CH₃)₂ H CD₃
 498. H CD(CD₃)₂ CD₃ H
 499. H CD(CD₃)₂ H CD₃
 500. CD₃ CD(CD₃)₂ CD₃ H
 501. CD₃ CD(CD₃)₂ H CD₃
 502. H CD(CD₃)₂ CD₃ CD₃
 503. CD₃ CD(CD₃)₂ CD₃ CD₃
 504. H H CD(CD₃)₃ H
 505. CD₃ H CD(CD₃)₂ H
 506. H CD₃ CD(CD₃)₂ H
 507. CD₃ CD₃ CD(CD₃)₂ CD₃
 508. CD₃ CD₃ CD(CD₃)₂ H
 509. CD₃ H CD(CD₃)₂ CD₃
 510. H CD₃ CD(CD₃)₂ CD₃
 511. CD₃ CD₃ CD(CD₃)₂ CD₃
 512. CD₂CH(CH₃)₂ H H H
 513. CD₂CH(CH₃)₂ CD₃ H CD₃
 514. CD₂CH(CH₃)₂ H CD₃ H
 515. CD₂CH(CH₃)₂ H H CD₃
 516. CD₂CH(CH₃)₂ CD₃ CD₃ H
 517. CD₂CH(CH₃)₂ CD₃ H CD₃
 518. CD₂CH(CH₃)₂ H CD₃ CD₃
 519. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃
 520. H CD₂CH(CH₃)₂ H H
 521. CD₃ CD₂CH(CH₃)₂ H CD₃
 522. H CD₂CH(CH₃)₂ CD₃ H
 523. H CD₂CH(CH₃)₂ H CD₃
 524. CD₃ CD₂CH(CH₃)₂ CD₃ H
 525. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 526. H CD₂CH(CH₃)₂ CD₃ CD₃
 527. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 528. H H CD₂CH(CH₃)₂ H
 529. CD₃ H CD₂CH(CH₃)₂ H
 530. H CD₃ CD₂CH(CH₃)₂ H
 531. H H CD₂CH(CH₃)₂ CD₃
 532. CD₃ CD₃ CD₂CH(CH₃)₂ H
 533. CD₃ H CD₂CH(CH₃)₂ CD₃
 534. H CD₃ CD₂CH(CH₃)₂ CD₃
 535. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃
 536. CD₂C(CH₃)₃ H H H
 537. CD₂C(CH₃)₃ CD₃ H CD₃
 538. CD₂C(CH₃)₃ H CD₃ H
 539. CD₂C(CH₃)₃ H H CD₃
 540. CD₂C(CH₃)₃ CD₃ CD₃ H
 541. CD₂C(CH₃)₃ CD₃ H CD₃
 542. CD₂C(CH₃)₃ H CD₃ CD₃
 543. CD₂C(CH₃)₃ CH₃ CD₃ CD₃
 544. H CD₂C(CH₃)₃ H H
 545. CD₃ CD₂C(CH₃)₃ H CD₃
 546. H CD₂C(CH₃)₃ CD₃ H
 547. H CD₂C(CH₃)₃ H CD₃
 548. CD₃ CD₂C(CH₃)₃ CD₃ H
 549. CD₃ CD₂C(CH₃)₃ H CD₃
 550. H CD₂C(CH₃)₃ CD₃ CD₃
 551. CD₃ CD₂C(CH₃)₃ CD₃ CD₃
 552. H H CD₂C(CH₃)₃ H
 553. CD₃ H CD₂C(CH₃)₃ H
 554. H CD₃ CD₂C(CH₃)₃ H
 555. H H CD₂C(CH₃)₃ CD₃
 556. CD₃ CD₃ CD₂C(CH₃)₃ H
 557. CD₃ H CD₂C(CH₃)₃ CD₃
 558. H CD₃ CD₂C(CH₃)₃ CD₃
 559. CD₃ CD₃ CD₂C(CH₃)₃ CD₃
 560. CD₂C(CH₃)₂CF₃ H H H
 561. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 562. CD₂C(CH₃)₂CF₃ H CD₃ H
 563. CD₂C(CH₃)₂CF₃ H H CD₃
 564. CD₂C(CH₃)₂CF₃ CD₃ CD₃ H
 565. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 566. CD₂C(CH₃)₂CF₃ H CD₃ CD₃
 567. CD₂C(CH₃)₂CF₃ CD₃ CD₃ CD₃
 568. H CD₂C(CH₃)₂CF₃ H H
 569. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 570. H CD₂C(CH₃)₂CF₃ CD₃ H
 571. H CD₂C(CH₃)₂CF₃ H CD₃
 572. CD₃ CD₂C(CH₃)₂CF₃ CD₃ H
 573. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 574. H CD₂C(CH₃)₂CF₃ CD₃ CD₃
 575. CD₃ CD₂C(CH₃)₂CF₃ CD₃ CD₃
 576. H H CD₂C(CH₃)₂CF₃ H
 577. CD₃ H CD₂C(CH₃)₂CF₃ H
 578. H CD₃ CD₂C(CH₃)₂CF₃ H
 579. H H CD₂C(CH₃)₂CF₃ CD₃
 580. CD₃ CD₃ CD₂C(CH₃)₂CF₃ H
 581. CD₃ H CD₂C(CH₃)₂CF₃ CD₃
 582. H CD₃ CD₂C(CH₃)₂CF₃ CD₃
 583. CD₃ CD₃ CD₂C(CH₃)₂CF₃ CD₃
 584. CD₂CH₂CF₃ H H H
 585. CD₂CH₂CF₃ CD₃ H CD₃
 586. CD₂CH₂CF₃ H CD₃ H
 587. CD₂CH₂CF₃ H H CD₃
 588. CD₂CH₂CF₃ CD₃ CH₃ H
 589. CD₂CH₂CF₃ CD₃ H CD₃
 590. CD₂CH₂CF₃ H CD₃ CD₃
 591. CD₂CH₂CF₃ CD₃ CD₃ CD₃
 592. H CD₂CH₂CF₃ H H
 593. CD₃ CD₂CH₂CF₃ H CD₃
 594. H CD₂CH₂CF₃ CD₃ H
 595. H CD₂CH₂CF₃ H CD₃
 596. CD₃ CD₂CH₂CF₃ CD₃ H
 597. CD₃ CD₂CH₂CF₃ H CD₃
 598. H CD₂CH₂CF₃ CD₃ CD₃
 599. CD₃ CD₂CH₂CF₃ CD₃ CD₃
 600. H H CD₂CH₂CF₃ H
 601. CD₃ H CD₂CH₂CF₃ H
 602. H CD₃ CD₂CH₂CF₃ H
 603. H H CD₂CH₂CF₃ CD₃
 604. CD₃ CD₃ CD₂CH₂CF₃ H
 605. CD₃ H CD₂CH₂CF₃ CD₃
 606. H CD₃ CD₂CH₂CF₃ CD₃
 607. CD₃ CD₃ CD₂CH₂CF₃ CD₃
 608.

H H H
 609.

CD₃ H CD₃
 610.

H CD₃ H
 611.

H H CD₃
 612.

CD₃ CD₃ H
 613.

CD₃ H CD₃
 614.

H CD₃ CD₃
 615.

CD₃ CD₃ CD₃
 616. H

H H
 617. CD₃

H CD₃
 618. H

CD₃ H
 619. H

H CD₃
 620. CD₃

CD₃ H
 621. CD₃

H CD₃
 622. H

CD₃ CD₃
 623. CD₃

CD₃ CD₃
 624. H H

H
 625. CD₃ H

H
 626. H CD₃

H
 627. H H

CD₃
 628. CD₃ CD₃

H
 629. CD₃ H

CD₃
 630. H CD₃

CD₃
 631. CD₃ CD₃

CD₃
 632.

H H H
 633.

CD₃ H CD₃
 634.

H CD₃ H
 635.

H H CD₃
 636.

CD₃ CD₃ H
 637.

CD₃ H CD₃
 638.

H CD₃ CD₃
 639.

CD₃ CD₃ CD₃
 640. H

H H
 641. CH₃

H CD₃
 642. H

CD₃ H
 643. H

H CD₃
 644. CD₃

CD₃ H
 645. CD₃

H CD₃
 646. H

CD₃ CD₃
 647. CH₃

CD₃ CD₃
 648. H H

H
 649. CD₃ H

H
 650. H CD₃

H
 651. H H

CD₃
 652. CD₃ CD₃

H
 653. CD₃ H

CD₃
 654. H CD₃

CD₃
 655. CD₃ CD₃

CD₃
 656.

H H H
 657.

CD₃ H CD₃
 658. +

H CD₃ H
 659.

H H CD₃
 660.

CD₃ CD₃ H
 661.

CD₃ H CD₃
 662.

H CD₃ CD₃
 663.

CD₃ CD₃ CD₃
 664. H

H H
 665. CD₃

H CD₃
 666. H

CD₃ H
 667. H

H CD₃
 668. CD₃

CD₃ H
 669. CD₃

H CD₃
 670. H

CD₃ CD₃
 671. CD₃

CD₃ CD₃
 672. H H

H
 673. CD₃ H

H
 674. H CD₃

H
 675. H H

CD₃
 676. CD₃ CD₃

H
 677. CD₃ H

CD₃
 678. H CD₃

CD₃
 679. CD₃ CD₃

CD₃
 680.

H H H
 681.

CD₃ H CD₃
 682.

H CD₃ H
 683.

H H CD₃
 684.

CD₃ CD₃ H
 685.

CD₃ H CD₃
 686.

H CD₃ CD₃
 687.

CD₃ CD₃ CD₃
 688. H

H H
 689. CD₃

H CD₃
 690. H

CD₃ H
 691. H

H CD₃
 692. CD₃

CD₃ H
 693. CD₃

H CD₃
 694. H

CD₃ CD₃
 695. CD₃

CD₃ CD₃
 696. H H

H
 697. CD₃ H

H
 698. H CD₃

H
 699. H H

CD₃
 700. CD₃ CD₃

H
 701. CD₃ H

CD₃
 702. H CD₃

CD₃
 703. CD₃ CD₃

CD₃
 704.

H H H
 705.

CD₃ H CD₃
 706.

H CD₃ H
 707.

H H CD₃
 708.

CD₃ CD₃ H
 709.

CD₃ H CD₃
 710.

H CD₃ CD₃
 711.

CD₃ CD₃ CD₃
 712. H

H H
 713. CD₃

H CD₃
 714. H

CD₃ H
 715. H

H CD₃
 716. CD₃

CD₃ H
 717. CD₃

H CD₃
 718. H

CD₃ CD₃
 719. CD₃

CD₃ CD₃
 720. H H

H
 721. CD₃ H

H
 722. H CD₃

H
 723. H H

CD₃
 724. CD₃ CD₃

H
 725. CD₃ H

CD₃
 726. H CD₃

CD₃
 727. CD₃ CD₃

CD₃
 728.

H H H
 729.

CD₃ H CD₃
 730.

H CD₃ H
 731.

H H CD₃
 732.

CH₃ CH₃ H
 733.

CD₃ H CD₃
 734.

H CD₃ CD₃
 735.

CD₃ CD₃ CD₃
 736. H

H H
 737. CD₃

H CD₃
 738. H

CD₃ H
 739. H

H CD₃
 740. CD₃

CD₃ H
 741. CD₃

H CD₃
 742. H

CD₃ CD₃
 743. CD₃

CD₃ CD₃
 744. H H

H
 745. CD₃ H

H
 746. H CD₃

H
 747. H H

CH₃
 748. CD₃ CD₃

H
 749. CD₃ H

CD₃
 750. H CD₃

CD₃
 751. CD₃ CD₃

CD₃
 752. CD(CH₃)₂ H CD₂CH₃ H
 753. CD(CH₃)₂ H CD(CH₃)₂ H
 754. CD(CH₃)₂ H CD₂CH(CH₃)₂ H
 755. CD(CH₃)₂ H C(CH₃)₃ H
 756. CD(CH₃)₂ H CD₂C(CH₃)₃ H
 757. CD(CH₃)₂ H CD₂CH₂CF₃ H
 758. CD(CH₃)₂ H CD₂C(CH₃)₂CF₃ H
 759. CD(CH₃)₂ H

H
 760. CD(CH₃)₂ H

H
 761. CD(CH₃)₂ H

H
 762. CD(CH₃)₂ H

H
 763. CD(CH₃)₂ H

H
 764. CD(CH₃)₂ H

H
 765. C(CH₃)₃ H CD₂CH₃ H
 766. C(CH₃)₃ H CD(CH₃)₂ H
 767. C(CH₃)₃ H CD₂CH(CH₃)₂ H
 768. C(CH₃)₃ H C(CH₃)₃ H
 769. C(CH₃)₃ H CD₂C(CH₃)₃ H
 770. C(CH₃)₃ H CD₂CH₂CF₃ H
 771. C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 772. C(CH₃)₃ H

H
 773. C(CH₃)₃ H

H
 774. C(CH₃)₃ H

H
 775. C(CH₃)₃ H

H
 776. C(CH₃)₃ H

H
 777. C(CH₃)₃ H

H
 778. CD₂C(CH₃)₃ H CD₂CH₃ H
 779. CD₂C(CH₃)₃ H CD(CH₃)₂ H
 780. CD₂C(CH₃)₃ H CD₂CH(CH₃)+₂ H
 781. CD₂C(CH₃)₃ H C(CH₃)₃ H
 782. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H
 783. CD₂C(CH₃)₃ H CD₂CH₂CF₃ H
 784. CD₂C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 785. CD₂C(CH₃)₃ H

H
 786. CD₂C(CH₃)₃ H

H
 787. CD₂C(CH₃)₃ H

H
 788. CD₂C(CH₃)₃ H

H
 789. CD₂C(CH₃)₃ H

H
 790. CD₂C(CH₃)₃ H

H
 791.

H CD₂CH₃ H
 792.

H CD(CH₃)₂ H
 793.

H CD₂CH(CH₃)₂ H
 794.

H C(CH₃)₃ H
 795.

H CD₂C(CH₃)₃ H
 796.

H CD₂CH₂CF₃ H
 797.

H CD₂C(CH₃)₂CF₃ H
 798.

H

H
 799.

H

H
 800.

H

H
 801.

H

H
 802.

H

H
 803.

H

H
 804.

H CD₂CH₃ H
 805.

H CD(CH₃)₂ H
 806.

H CD₂CH(CH₃)₂ H
 807.

H C(CH₃)₃ H
 808.

H CD₂C(CH₃)₃ H
 809.

H CD₂CH₂CF₃ H
 810.

H CD₂C(CH₃)₂CF₃ H
 811.

H

H
 812.

H

H
 813.

H

H
 814.

H

H
 815.

H

H
 816.

H

H
 817.

H CD₃CH₃ H
 818.

H CD(CH₃)₂ H
 819.

H CD₂CH(CH₃)₂ H
 820.

H C(CH₃)₃ H
 821.

H CD₂C(CH₃)₃ H
 822.

H CD₂CH₂CF₃ H
 823.

H CD₂C(CH₃)₂CF₃ H
 824.

H

H
 825.

H

H
 826.

H

H
 827.

H

H
 828.

H

H
 829.

H

H
 830.

H CD₂CH₃ H
 831.

H CD(CH₃)₂ H
 832.

H CD₂CH(CH₃)₂ H
 833.

H C(CH₃)₃ H
 834.

H CD₂C(CH₃)₃ H
 835.

H CD₂CH₂CF₃ H
 836.

H CD₂C(CH₃)₂CF₃ H
 837.

H

H
 838.

H

H
 839.

H

H
 840.

H

H
 841.

H

H
 842.

H

H
 843.

H CD₂CH₃ H
 844.

H CD(CH₃)₂ H
 845.

H CD₂CH(CH₃)₂ H
 846.

H C(CH₃)₃ H
 847.

H CD₂C(CH₃)₃ H
 848.

H CD₂CH₂CF₃ H
 849.

H CD₂C(CH₃)₂CF₃ H
 850.

H

H
 851.

H

H
 852.

H

H
 853.

H

H
 854.

H

H
 855.

H

H


12. The compound of claim 11, wherein the compound is selected from the group consisting of Compound 1 through Compound 1,082,872, wherein: (I) for Compound 1 through Compound 542,070, Compound x has the formula Ir(L_(Ap,i))(L_(Bj))₂; where x=854i+j−854; i is an integer from 1 to 634, and j is an integer from 1 to 855, and (II) for Compound 542,071 through Compound 1,084,140, Compound x has the formula Ir(L_(Am,i))(L_(Bj))₂; where x=854i+j+541,216; i is an integer from 1 to 634, and j is an integer from 1 to 855; and wherein L_(Ap,1) to L_(Ap,634) and L_(Am,1) to L_(m,634), have structures

where R^(A1), R^(A2), R^(A3), and R^(A4) are defined as follows: i R^(A1) R^(A2) R^(A3) R^(A4)
 1. CH₃ H H H
 2. CH₃ CH₃ H CH₃
 3. CH₃ H CH₃ H
 4. CH₃ H H CH₃
 5. CH₃ CH₃ CH₃ H
 6. CH₃ CH₃ H CH₃
 7. CH₃ H CH₃ CH₃
 8. CH₃ CH₃ CH₃ CH₃
 9. CH₂CH₃ H H H
 10. CH₂CH₃ CH₃ H CH₃
 11. CH₂CH₃ H CH₃ H
 12. CH₂CH₃ H H CH₃
 13. CH₂CH₃ CH₃ CH₃ H
 14. CH₂CH₃ CH₃ H CH₃
 15. CH₂CH₃ H CH₃ CH₃
 16. CH₂CH₃ CH₃ CH₃ CH₃
 17. CH₃ CH₂CH₃ H CH₃
 18. CH₃ CH₂CH₃ CH₃ H
 19. CH₃ CH₂CH₃ H CH₃
 20. CH₃ CH₂CH₃ CH₃ CH₃
 21. CH₃ H CH₂CH₃ H
 22. CH₃ CH₃ CH₂CH₃ H
 23. CH₃ H CH₂CH₃ CH₃
 24. CH₃ CH₃ CH₂CH₃ CH₃
 25. CH(CH₃)₂ H H H
 26. CH(CH₃)₂ CH₃ H CH₃
 27. CH(CH₃)₂ H CH₃ H
 28. CH(CH₃)₂ H H CH₃
 29. CH(CH₃)₂ CH₃ CH₃ H
 30. CH(CH₃)₂ CH₃ H CH₃
 31. CH(CH₃)₂ H CH₃ CH₃
 32. CH(CH₃)₂ CH₃ CH₃ CH₃
 33. CH₃ CH(CH₃)₂ H CH₃
 34. CH₃ CH(CH₃)₂ CH₃ H
 35. CH₃ CH(CH₃)₂ H CH₃
 36. CH₃ CH(CH₃)₂ CH₃ CH₃
 37. CH₃ H CH(CH₃)₂ H
 38. CH₃ CH₃ CH(CH₃)₂ H
 39. CH₃ H CH(CH₃)₂ CH₃
 40. CH₃ CH₃ CH(CH₃)₂ CH₃
 41. CH₂CH(CH₃)₂ H H H
 42. CH₂CH(CH₃)₂ CH₃ H CH₃
 43. CH₂CH(CH₃)₂ H CH₃ H
 44. CH₂CH(CH₃)₂ H H CH₃
 45. CH₂CH(CH₃)₂ CH₃ CH₃ H
 46. CH₂CH(CH₃)₂ CH₃ H CH₃
 47. CH₂CH(CH₃)₂ H CH₃ CH₃
 48. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃
 49. CH₃ CH₂CH(CH₃)₂ H CH₃
 50. CH₃ CH₂CH(CH₃)₂ CH₃ H
 51. CH₃ CH₂CH(CH₃)₂ H CH₃
 52. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃
 53. CH₃ H CH₂CH(CH₃)₂ H
 54. CH₃ CH₃ CH₂CH(CH₃)₂ H
 55. CH₃ H CH₂CH(CH₃)₂ CH₃
 56. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃
 57. C(CH₃)₃ H H H
 58. C(CH₃)₃ CH₃ H CH₃
 59. C(CH₃)₃ H CH₃ H
 60. C(CH₃)₃ H H CH₃
 61. C(CH₃)₃ CH₃ CH₃ H
 62. C(CH₃)₃ CH₃ H CH₃
 63. C(CH₃)₃ H CH₃ CH₃
 64. C(CH₃)₃ CH₃ CH₃ CH₃
 65. CH₃ C(CH₃)₃ H CH₃
 66. CH₃ C(CH₃)₃ CH₃ H
 67. CH₃ C(CH₃)₃ H CH₃
 68. CH₃ C(CH₃)₃ CH₃ CH₃
 69. CH₃ H C(CH₃)₃ H
 70. CH₃ CH₃ C(CH₃)₃ H
 71. CH₃ H C(CH₃)₃ CH₃
 72. CH₃ CH₃ C(CH₃)₃ CH₃
 73. CH₂C(CH₃)₃ H H H
 74. CH₂C(CH₃)₃ CH₃ H CH₃
 75. CH₂C(CH₃)₃ H CH₃ H
 76. CH₂C(CH₃)₃ H H CH₃
 77. CH₂C(CH₃)₃ CH₃ CH₃ H
 78. CH₂C(CH₃)₃ CH₃ H CH₃
 79. CH₂C(CH₃)₃ H CH₃ CH₃
 80. CH₂C(CH₃)₃ CH₃ CH₃ CH₃
 81. CH₃ CH₂C(CH₃)₃ H CH₃
 82. CH₃ CH₂C(CH₃)₃ CH₃ H
 83. CH₃ CH₂C(CH₃)₃ H CH₃
 84. CH₃ CH₂C(CH₃)₃ CH₃ CH₃
 85. CH₃ H CH₂C(CH₃)₃ H
 86. CH₃ CH₃ CH₂C(CH₃)₃ H
 87. CH₃ H CH₂C(CH₃)₃ CH₃
 88. CH₃ CH₃ CH₂C(CH₃)₃ CH₃
 89. CH₂C(CH₃)₂CF₃ H H H
 90. CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 91. CH₂C(CH₃)₂CF₃ H CH₃ H
 92. CH₂C(CH₃)₂CF₃ H H CH₃
 93. CH₂C(CH₃)₂CF₃ CH₃ CH₃ H
 94. CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 95. CH₂C(CH₃)₂CF₃ H CH₃ CH₃
 96. CH₂C(CH₃)₂CF₃ CH₃ CH₃ CH₃
 97. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 98. CH₃ CH₂C(CH₃)₂CF₃ CH₃ H
 99. CH₃ CH₂C(CH₃)₂CF₃ H CH₃
 100. CH₃ CH₂C(CH₃)₂CF₃ CH₃ CH₃
 101. CH₃ H CH₂C(CH₃)₂CF₃ H
 102. CH₃ CH₃ CH₂C(CH₃)₂CF₃ H
 103. CH₃ H CH₂C(CH₃)₂CF₃ CH₃
 104. CH₃ CH₃ CH₂C(CH₃)₂CF₃ CH₃
 105. CH₂CH₂CF₃ H H H
 106. CH₂CH₂CF₃ CH₃ H CH₃
 107. CH₂CH₂CF₃ H CH₃ H
 108. CH₂CH₂CF₃ H H CH₃
 109. CH₂CH₂CF₃ CH₃ CH₃ H
 110. CH₂CH₂CF₃ H CH₃
 111. CH₂CH₂CF₃ H CH₃ CH₃
 112. CH₂CH₂CF₃ CH₃ CH₃ CH₃
 113. CH₃ CH₂CH₂CF₃ H CH₃
 114. CH₃ CH₂CH₂CF₃ CH₃ H
 115. CH₃ CH₂CH₂CF₃ H CH₃
 116. CH₃ CH₂CH₂CF₃ CH₃ CH₃
 117. CH₃ H CH₂CH₂CF₃ H
 118. CH₃ CH₃ CH₂CH₂CF₃ H
 119. CH₃ H CH₂CH₂CF₃ CH₃
 120. CH₃ CH₃ CH₂CH₂CF₃ CH₃
 121.

H H H
 122.

CH₃ H CH₃
 123.

H CH₃ H
 124.

H H CH₃
 125.

CH₃ CH₃ H
 126.

CH₃ H CH₃
 127.

H CH₃ CH₃
 128.

CH₃ CH₃ CH₃
 129. CH₃

H CH₃
 130. CH₃

CH₃ H
 131. CH₃

H CH₃
 132. CH₃

CH₃ CH₃
 133. CH₃ H

H
 134. CH₃ CH₃

H
 135. CH₃ H

CH₃
 136. CH₃ CH₃

CH₃
 137.

H H H
 138.

CH₃ H CH₃
 139.

H CH₃ H
 140.

H H CH₃
 141.

CH₃ CH₃ H
 142.

CH₃ H CH₃
 143.

H CH₃ CH₃
 144.

CH₃ CH₃ CH₃
 145. CH₃

H CH₃
 146. CH₃

CH₃ H
 147. CH₃

H CH₃
 148. CH₃

CH₃ CH₃
 149. CH₃ H

H
 150. CH₃ CH₃

H
 151. CH₃ H

CH₃
 152. CH₃ CH₃

CH₃
 153.

H H H
 154.

CH₃ H CH₃
 155.

H CH₃ H
 156.

H H CH₃
 157.

CH₃ CH₃ H
 158.

CH₃ H CH₃
 159.

H CH₃ CH₃
 160.

CH₃ CH₃ CH₃
 161. CH₃

H CH₃
 162. CH₃

CH₃ H
 163. CH₃

H CH₃
 164. CH₃

CH₃ CH₃
 165. CH₃ H

H
 166. CH₃ CH₃

H
 167. CH₃ H

CH₃
 168. CH₃ CH₃

CH₃
 169.

H H H
 170.

CH₃ H CH₃
 171.

H CH₃ H
 172.

H H CH₃
 173.

CH₃ CH₃ H
 174.

CH₃ H CH₃
 175.

H CH₃ CH₃
 176.

CH₃ CH₃ CH₃
 177. CH₃

H CH₃
 178. CH₃

CH₃ H
 179. CH₃

H CH₃
 180. CH₃

CH₃ CH₃
 181. CH₃ H

H
 182. CH₃ CH₃

H
 183. CH₃ H

CH₃
 184. CH₃ CH₃

CH₃
 185.

H H H
 186.

CH₃ H CH₃
 187.

H CH₃ H
 188.

H H CH₃
 189.

CH₃ CH₃ H
 190.

CH₃ H CH₃
 191.

H CH₃ CH₃
 192.

CH₃ CH₃ CH₃
 193. CH₃

H CH₃
 194. CH₃

CH₃ H
 195. CH₃

H CH₃
 196. CH₃

CH₃ CH₃
 197. CH₃ H

H
 198. CH₃ CH₃

H
 199. CH₃ H

CH₃
 200. CH₃ CH₃

CH₃
 201.

H H H
 202.

CH₃ H CH₃
 203.

H CH₃ H
 204.

H H CH₃
 205.

CH₃ CH₃ H
 206.

CH₃ H CH₃
 207.

H CH₃ CH₃
 208.

CH₃ CH₃ CH₃
 209. CH₃

H CH₃
 210. CH₃

CH₃ H
 211. CH₃

H CH₃
 212. CH₃

CH₃ CH₃
 213. CH₃ H

H
 214. CH₃ CH₃

H
 215. CH₃ H

CH.,
 216. CH₃ CH₃

CH₃
 217. CH(CH₃)₂ H CH₂CH₃ H
 218. CH(CH₃)₂ H CH(CH₃)₂ H
 219. CH(CH₃)₂ H CH₂CH(CH₃)₂ H
 220. CH(CH₃)₂ H C(CH₃)₃ H
 221. CH(CH₃)₂ H CH₂C(CH₃)₃ H
 222. CH(CH₃)₂ H CH₂CH₂CF₃ H
 223. CH(CH₃)₂ H CH₂C(CH₃)₂CF₃ H
 224. CH(CH₃)₂ H

H
 225. CH(CH₃)₂ H

H
 226. CH(CH₃)₂ H

H
 227. CH(CH₃)₂ H

H
 228. CH(CH₃)₂ H

H
 229. CH(CH₃)₂ H

H
 230. C(CH₃)₃ H CH₂CH₃ H
 231. C(CH₃)₃ H CH(CH₃)₂ H
 232. C(CH₃)₃ H CH₂CH(CH₃)₂ H
 233. C(CH₃)₃ H C(CH₃)₃ H
 234. C(CH₃)₃ H CH₂C(CH₃)₃ H
 235. C(CH₃)₃ H CH₂CH₂CF₃ H
 236. C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 237. C(CH₃)₃ H

H
 238. C(CH₃)₃ H

H
 239. C(CH₃)₃ H

H
 240. C(CH₃)₃ H

H
 241. C(CH₃)₃ H

H
 242. C(CH₃)₃ H

H
 243. CH₂C(CH₃)₃ H CH₂CH₃ H
 244. CH₂C(CH₃)₃ H CH(CH₃)₂ H
 245. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H
 246. CH₂C(CH₃)₃ H C(CH₃)₃ H
 247. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H
 248. CH₂C(CH₃)₃ H CH₂CH₂CF₃ H
 249. CH₂C(CH₃)₃ H CH₂C(CH₃)₂CF₃ H
 250. CH₂C(CH₃)₃ H

H
 251. CH₂C(CH₃)₃ H

H
 252. CH₂C(CH₃)₃ H

H
 253. CH₂C(CH₃)₃ H

H
 254. CH₂C(CH₃)₃ H

H
 255. CH₂C(CH₃)₃ H

H
 256.

H CH₂CH₃ H
 257.

H CH(CH₃)₂ H
 258.

H CH₂CH(CH₃)₂ H
 259.

H C(CH₃)₃ H
 260.

H CH₂C(CH₃)₃ H
 261.

H CH₂CH₂CF₃ H
 262.

H CH₂C(CH₃)₂CF₃ H
 263.

H

H
 264.

H

H
 265.

H

H
 266.

H

H
 267.

H

H
 268.

H

H
 269.

H CH₂CH₃ H
 270.

H CH(CH₃)₂ H
 271.

H CH₂CH(CH₃)₂ H
 272.

H C(CH₃)₃ H
 273.

H CH₂C(CH₃)₃ H
 274.

H CH₂CH₂CF₃ H
 275.

H CH₂C(CH₃)₂CF₃ H
 276.

H

H
 277.

H

H
 278.

H

H
 279.

H

H
 280.

H

H
 281.

H

H
 282.

H CH₂CH(CH₃)₂ H
 283.

H C(CH₃)₃ H
 284.

H CH₂C(CH₃)₃ H
 285.

H CH₂CH₂CF₃ H
 286.

H CH₂C(CH₃)₂CF₃ H
 287.

H

H
 288.

H

H
 289.

H

H
 290.

H

H
 291.

H

H
 292.

H

H
 293.

H CH₂CH(CH₃)₂ H
 294.

H C(CH₃)₃ H
 295.

H CH₂C(CH₃)₃ H
 296.

H CH₂CH₂CF₃ H
 297.

H CH₂C(CH₃)₂CF₃ H
 298.

H

H
 299.

H

H
 300.

H

H
 301.

H

H
 302.

H

H
 303.

H

H
 304.

H CH₂CH(CH₃)₂ H
 305.

H C(CH₃)₃ H
 306.

H CH₂C(CH₃)₃ H
 307.

H CH₂CH₂CF₃ H
 308.

H CH₂C(CH₃)₂CF₃ H
 309.

H

H
 310.

H

H
 311.

H

H
 312.

H

H
 313.

H

H
 314.

H

H
 315. CD₃ H H H
 316. CD₃ CD₃ H CD₃
 317. CD₃ H CD₃ H
 318. CD₃ H H CD₃
 319. CD₃ CD₃ CD₃ H
 320. CD₃ CD₃ H CD₃
 321. CD₃ H CD₃ CD₃
 322. CD₃ CD₃ CD₃ CD₃
 323. CD₂CH₃ H H H
 324. CD₂CH₃ CD₃ H CD₃
 325. CD₂CH₃ H CD₃ H
 326. CD₂CH₃ H H CD₃
 327. CD₂CH₃ CD₃ CD₃ H
 328. CD₂CH₃ CD₃ H CD₃
 329. CD₂CH₃ H CD₃ CD₃
 330. CD₂CH₃ CD₃ CD₃ CD₃
 331. CH₃ CD₂CH₃ H CD₃
 332. CD₃ CD₂CH₃ CD₃ H
 333. CD₃ CD₂CH₃ H CD₃
 334. CD₃ CD₂CH₃ CD₃ CD₃
 335. CD₃ H CD₂CH₃ H
 336. CD₃ CD₃ CD₂CH₃ H
 337. CD₃ H CD₂CH₃ CD₃
 338. CD₃ CD₃ CD₂CH₃ CD₃
 339. CD(CH₃)₂ H H H
 340. CD(CH₃)₂ CD₃ H CD₃
 341. CD(CH₃)₂ H CD₃ H
 342. CD(CH₃)₂ H H CD₃
 343. CD(CH₃)₂ CD₃ CD₃ H
 344. CD(CH₃)₂ CD₃ H CD₃
 345. CD(CH₃)₂ H CD₃ CD₃
 346. CD(CH₃)₂ CD₃ CD₃ CD₃
 347. CD₃ CD(CH₃)₂ H CD₃
 348. CD₃ CD(CH₃)₂ CD₃ H
 349. CD₃ CD(CH₃)₂ H CD₃
 350. CD₃ CD(CH₃)₂ CD₃ CD₃
 351. CD₃ H CD(CH₃)₂ H
 352. CD₃ CD₃ CD(CH₃)₂ H
 353. CD₃ H CD(CH₃)₂ CD₃
 354. CD₃ CD₃ CD(CH₃)₂ CD₃
 355. CD(CD₃)₂ H H H
 356. CD(CD₃)₂ CD₃ H CD₃
 357. CD(CD₃)₂ H CD₃ H
 358. CD(CD₃)₂ H H CD₃
 359. CD(CD₃)₂ CD₃ CD₃ H
 360. CD(CD₃)₂ CD₃ H CD₃
 361. CD(CD₃)₂ H CD₃ CD₃
 362. CD(CD₃)₂ CD₃ CD₃ CD₃
 363. CH₃ CD(CD₃)₂ H CD₃
 364. CD₃ CD(CD₃)₂ CD₃ H
 365. CD₃ CD(CD₃)₂ H CD₃
 366. CD₃ CD(CD₃)₂ CD₃ CD₃
 367. CD₃ H CD(CD₃)₂ H
 368. CD₃ CD₃ CD(CD₃)₂ H
 369. CD₃ H CD(CD₃)₂ CD₃
 370. CD₃ CD₃ CD(CD₃)₂ CD₃
 371. CD₂CH(CH₃)₂ H H H
 372. CD₂CH(CH₃)₂ CD₃ H CD₃
 373. CD₂CH(CH₃)₂ H CD₃ H
 374. CD₂CH(CH₃)₂ H H CD₃
 375. CD₂CH(CH₃)₂ CD₃ CD₃ H
 376. CD₂CH(CH₃)₂ CD₃ H CD₃
 377. CD₂CH(CH₃)₂ H CD₃ CD₃
 378. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃
 379. CD₃ CD₂CH(CH₃)₂ H CD₃
 380. CD₃ CD₂CH(CH₃)₂ CD₃ H
 381. CD₃ CD₂CH(CH₃)₂ H CD₃
 382. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 383. CD₃ H CD₂CH(CH₃)₂ H
 384. CD₃ CD₃ CD₂CH(CH₃)₂ H
 385. CD₃ H CD₂CH(CH₃)₂ CD₃
 386. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃
 387. CD₂C(CH₃)₃ H H H
 388. CD₂C(CH₃)₃ CD₃ H CD₃
 389. CD₂C(CH₃)₃ H CD₃ H
 390. CD₂C(CH₃)₃ H H CD₃
 391. CD₂C(CH₃)₃ CD₃ CD₃ H
 392. CD₂C(CH₃)₃ CD₃ H CD₃
 393. CD₂C(CH₃)₃ H CD₃ CD₃
 394. CD₂C(CH₃)₃ CH₃ CD₃ CD₃
 395. CD₃ CD₂C(CH₃)₃ H CD₃
 396. CD₃ CD₂C(CH₃)₃ CD₃ H
 397. CD₃ CD₂C(CH₃)₃ H CD₃
 398. CD₃ CD₂C(CH₃)₃ CD₃ CD₃
 399. CD₃ H CD₂C(CH₃)₃ H
 400. CD₃ CD₃ CD₂C(CH₃)₃ H
 401. CD₃ H CD₂C(CH₃)₃ CD₃
 402. CD₃ CD₃ CD₂C(CH₃)₃ CD₃
 403. CD₂C(CH₃)₂CF₃ H H H
 404. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 405. CD₂C(CH₃)₂CF₃ H CD₃ H
 406. CD₂C(CH₃)₂CF₃ H H CD₃
 407. CD₂C(CH₃)₂CF₃ CD₃ CD₃ H
 408. CD₂C(CH₃)₂CF₃ CD₃ H CD₃
 409. CD₂C(CH₃)₂CF₃ H CD₃ CD₃
 410. CD₂C(CH₃)₂CF₃ CD₃ CD₃ CD₃
 411. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 412. CD₃ CD₂C(CH₃)₂CF₃ CD₃ H
 413. CD₃ CD₂C(CH₃)₂CF₃ H CD₃
 414. CD₃ CD₂C(CH₃)₂CF₃ CD₃ CD₃
 415. CD₃ H CD₂C(CH₃)₂CF₃ H
 416. CD₃ CD₃ CD₂C(CH₃)₂CF₃ H
 417. CD₃ H CD₂C(CH₃)₂CF₃ CD₃
 418. CD₃ CD₃ CD₂C(CH₃)₂CF₃ CD₃
 419. CD₂CH₂CF₃ H H H
 420. CD₂CH₂CF₃ CD₃ H CD₃
 421. CD₂CH₂CF₃ H CD₃ H
 422. CD₂CH₂CF₃ H H CD₃
 423. CD₂CH₂CF₃ CD₃ CD₃ H
 424. CD₂CH₂CF₃ CD₃ H CD₃
 425. CD₂CH₂CF₃ H CD₃ CD₃
 426. CD₂CH₂CF₃ CD₃ CD₃ CD₃
 427. CD₃ CD₂CH₂CF₃ H CD₃
 428. CD₃ CD₂CH₂CF₃ CD₃ H
 429. CD₃ CD₂CH₂CF₃ H CD₃
 430. CD₃ CD₂CH₂CF₃ CD₃ CD₃
 431. CD₃ H CD₂CH₂CF₃ H
 432. CD₃ CD₃ CD₂CH₂CF₃ H
 433. CD₃ H CD₂CH₂CF₃ CD₃
 434. CD₃ CD₃ CD₂CH₂CF₃ CD₃
 435.

H H H
 436.

CD₃ H CD₃
 437.

H CD₃ H
 438.

H H CD₃
 439.

CD₃ CD₃ H
 440.

CD₃ H CD₃
 441.

H CD₃ CD₃
 442.

CD₃ CD₃ CD₃
 443. CD₃

H CD₃
 444. CD₃

CD₃ H
 445. CD₃

H CD₃
 446. CD₃

CD₃ CD₃
 447. CD₃ H

H
 448. CD₃ CD₃

H
 449. CD₃ H

CD₃
 450. CD₃ CD₃

CD₃
 451.

H H H
 452.

CD₃ H CD₃
 453.

H CD₃ H
 454.

H H CD₃
 455.

CD₃ CD₃ H
 456.

CD₃ H CD₃
 457.

H CD₃ CD₃
 458.

CD₃ CD₃ CD₃
 459. CH₃

H CD₃
 460. CD₃

CD₃ H
 461. CD₃

H CD₃
 462. CH₃

CD₃ CD₃
 463. CD₃ H

H
 464. CD₃ CD₃

H
 465. CD₃ H

CD₃
 466. CD₃ CD₃

CD₃
 467.

H H H
 468.

CD₃ H CD₃
 469.

H CD₃ H
 470.

H H CD₃
 471.

CD₃ CD₃ H
 472.

CD₃ H CD₃
 473.

H CD₃ CD₃
 474.

CD₃ CD₃ CD₃
 475. CD₃

H CD₃
 476. CD₃

CD₃ H
 477. CD₃

H CD₃
 478. CD₃

CD₃ CD₃
 479. CD₃ H

H
 480. CD₃ CD₃

H
 481. CD₃ H

CD₃
 482. CD₃ CD₃

CD₃
 483.

H H H
 484.

CD₃ H CD₃
 485.

H CD₃ H
 486.

H H CD₃
 487.

CD₃ CD₃ H
 488.

CD₃ H CD₃
 489.

H CD₃ CD₃
 490.

CD₃ CD₃ CD₃
 491. CD₃

H CD₃
 492. CD₃

CD₃ H
 493. CD₃

H CD₃
 494. CD₃

CD₃ CD₃
 495. CD₃ H

H
 496. CD₃ CD₃

H
 497. CD₃ H

CD₃
 498. CD₃ CD₃

CD₃
 499.

H H H
 500.

CD₃ H CD₃
 501.

H CD₃ H
 502.

H H CD₃
 503.

CD₃ CD₃ H
 504.

CD₃ H CD₃
 505.

H CD₃ CD₃
 506.

CD₃ CD₃ CD₃
 507. CD₃

H CD₃
 508. CD₃

CD₃ H
 509. CD₃

H CD₃
 510. CD₃

CD₃ CD₃
 511. CD₃ H

H
 512. CD₃ CD₃

H
 513. CD₃ H

CD₃
 514. CD₃ CD₃

CD₃
 515.

H H H
 516.

CD₃ H CD₃
 517.

H CD₃ H
 518.

H H CD₃
 519.

CH₃ CH₃ H
 520.

CD₃ H CD₃
 521.

H CD₃ CD₃
 522.

CD₃ CD₃ CD₃
 523. CD₃

H CD₃
 524. CD₃

CD₃ H
 525. CD₃

H CD₃
 526. CD₃

CD₃ CD₃
 527. CD₃ H

H
 528. CD₃ CD₃

H
 529. CD₃ H

CD₃
 530. CD₃ CD₃

CD₃
 531. CD(CH₃)₂ H CD₂CH₃ H
 532. CD(CH₃)₂ H CD(CH₃)₂ H
 533. CD(CH₃)₂ H CD₂CH(CH₃)₂ H
 534. CD(CH₃)₂ H C(CH₃)₃ H
 535. CD(CH₃)₂ H CD₂C(CH₃)₃ H
 536. CD(CH₃)₂ H CD₂CH₂CF₃ H
 537. CD(CH₃)₂ H CD₂C(CH₃)₂CF₃ H
 538. CD(CH₃)₂ H

H
 539. CD(CH₃)₂ H

H
 540. CD(CH₃)₂ H

H
 541. CD(CH₃)₂ H

H
 542. CD(CH₃)₂ H

H
 543. CD(CH₃)₂ H

H
 544. C(CH₃)₃ H CD₂CH₃ H
 545. C(CH₃)₃ H CD(CH₃)₂ H
 546. C(CH₃)₃ H CD₂CH(CH₃)₂ H
 547. C(CH₃)₃ H C(CH₃)₃ H
 548. C(CH₃)₃ H CD₂C(CH₃)₃ H
 549. C(CH₃)₃ H CD₂CH₂CF₃ H
 550. C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 551. C(CH₃)₃ H

H
 552. C(CH₃)₃ H

H
 553. C(CH₃)₃ H

H
 554. C(CH₃)₃ H

H
 555. C(CH₃)₃ H

H
 556. C(CH₃)₃ H

H
 557. CD₂C(CH₃)₃ H CD₂CH₃ H
 558. CD₂C(CH₃)₃ H CD(CH₃)₂ H
 559. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H
 560. CD₂C(CH₃)₃ H C(CH₃)₃ H
 561. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H
 562. CD₂C(CH₃)₃ H CD₂CH₂CF₃ H
 563. CD₂C(CH₃)₃ H CD₂C(CH₃)₂CF₃ H
 564. CD₂C(CH₃)₃ H

H
 565. CD₂C(CH₃)₃ H

H
 566. CD₂C(CH₃)₃ H

H
 567. CD₂C(CH₃)₃ H

H
 568. CD₂C(CH₃)₃ H

H
 569. CD₂C(CH₃)₃ H

H
 570.

H CD₂CH₃ H
 571.

H CD(CH₃)₂ H
 572.

H CD₂CH(CH₃)₂ H
 573.

H C(CH₃)₃ H
 574.

H CD₂C(CH₃)₃ H
 575.

H CD₂CH₂CF₃ H
 576.

H CD₂C(CH₃)₂CF₃ H
 577.

H

H
 578.

H

H
 579.

H

H
 580.

H

H
 581.

H

H
 582.

H

H
 583.

H CD₂CH₃ H
 584.

H CD(CH₃)₂ H
 585.

H CD₂CH(CH₃)₂ H
 586.

H C(CH₃)₃ H
 587.

H CD₂C(CH₃)₃ H
 588.

H CD₂CH₂CF₃ H
 589.

H CD₂C(CH₃)₂CF₃ H
 590.

H

H
 591.

H

H
 592.

H

H
 593.

H

H
 594.

H

H
 595.

H

H
 596.

H CD₂CH₃ H
 597.

H CD(CH₃)₂ H
 598.

H CD₂CH(CH₃)₂ H
 599.

H C(CH₃)₃ H
 600.

H CD₂C(CH₃)₃ H
 601.

H CD₂CH₂CF₃ H
 602.

H CD₂C(CH₃)₂CF₃ H
 603.

H

H
 604.

H

H
 605.

H

H
 606.

H

H
 607.

H

H
 608.

H

H
 609.

H CD₂CH₃ H
 610.

H CD(CH₃)₂ H
 611.

H CD₂CH(CH₃)₂ H
 612.

H C(CH₃)₃ H
 613.

H CD₂C(CH₃)₃ H
 614.

H CD₂CH₂CF₃ H
 615.

H CD₂C(CH₃)₂CF₃ H
 616.

H

H
 617.

H

H
 618.

H

H
 619.

H

H
 620.

H

H
 621.

H

H
 622.

H CD₂CH₃ H
 623.

H CD(CH₃)₂ H
 624.

H CD₂CH(CH₃)₂ H
 625.

H C(CH₃)₃ H
 626.

H CD₂C(CH₃)₃ H
 627.

H CD₂CH₂CF₃ H
 628.

H CD₂C(CH₃)₂CF₃ H
 629.

H

H
 630.

H

H
 631.

H

H
 632.

H

H
 633.

H

H
 634.

H

H


13. An organic light emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n), having the structure:

wherein each of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is independently carbon or nitrogen; wherein at least one of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is nitrogen; wherein ring B is bonded to ring A through a C—C bond; wherein the iridium is bonded to ring A through an Ir—C bond; wherein X is O, S, or Se; wherein R¹, R², R³, R⁴, and R⁵ independently represent from mono-substituted to the maximum possibly substitutions, or no substitution; wherein any adjacent substitutions in R¹, R², R³, R⁴, and R⁵ are optionally linked together to form a ring; wherein R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein n is an integer from 1 to 3; and wherein at least one R² adjacent to ring C is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variations thereof, partially or fully fluorinated variations thereof, and combinations thereof.
 14. The OLED of claim 13, wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
 15. The OLED of claim 13, wherein the organic layer further comprises a host, wherein the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan; wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1), C≡CC_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁; wherein n is from 1 to 10; and wherein Ar₁ and Ar₂ are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.
 16. The OLED of claim 13, wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
 17. The OLED of claim 13, wherein the organic layer further comprises a host, wherein the host is selected from the group consisting of:

and combinations thereof.
 18. The OLED of claim 13, wherein the organic layer further comprises a host, wherein the host comprises a metal complex.
 19. A consumer product comprising an organic light-emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula Ir(L_(A))_(n)(L_(B))_(3-n), having the structure:

wherein each of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is independently carbon or nitrogen; wherein at least one of A¹, A², A³, A⁴, A⁵, A⁶, A⁷, and A⁸ is nitrogen; wherein ring B is bonded to ring A through a C—C bond; wherein the iridium is bonded to ring A through an h-C bond; wherein X is O, S, or Se; wherein R¹, R², R³, R⁴, and R⁵ independently represent from mono-substituted to the maximum possibly substitutions, or no substitution; wherein any adjacent substitutions in R¹, R², R³, R′, and R⁵ are optionally linked together to form a ring; wherein R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfonyl, sulfonyl, phosphino, and combinations thereof; wherein n is an integer from 1 to 3; and wherein at least one R² adjacent to ring C is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variations thereof, partially or fully fluorinated variations thereof, and combinations thereof.
 20. The consumer product in claim 19, wherein the consumer product is selected from the group consisting of flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, and a sign. 